Carbon Materials as Catalytic Tools for Oxidative Dehydrogenations and Couplings in Liquid Phase

Anna Lenarda; Tom Wirtanen; Juho Helaja

doi:10.1055/a-1931-0749

Synthesis, Table of Contents

Synthesis 2023; 55(01): 45-61
DOI: 10.1055/a-1931-0749

short review

Carbon Materials as Catalytic Tools for Oxidative Dehydrogenations and Couplings in Liquid Phase

Authors

Anna Lenarda∗

^aDepartment of Chemistry, University of Helsinki, A. I. Virtasen aukio 1, P.O. Box 55, 00014 Helsinki, Finland
Tom Wirtanen∗

^bVTT Technical Research Centre of Finland Ltd., P.O. Box 1000, 02044 Espoo, Finland
Juho Helaja ∗

^aDepartment of Chemistry, University of Helsinki, A. I. Virtasen aukio 1, P.O. Box 55, 00014 Helsinki, Finland

Abstract

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Abstract

Carbocatalysis is a heterogeneous metal-free catalytic technique of high potential for current and future synthetic processes. Carbocatalysts entail heterogeneous materials based on sp²/sp³ interconnected carbons decorated with oxygen functional groups, defects, and other heteroatom dopants. In this short review, we cover a wide range of different carbocatalyzed oxidative dehydrogenation reactions, with particular emphasis on liquid-phase transformations that are relevant for synthetic organic chemists.

1 Introduction

2 Structures of Catalytic Carbon Materials

3 Oxidative Aromatizations with Activated Carbon

4 Oxidative Dehydrogenation CH–CH Couplings

5 Oxidative Dehydrogenation Coupling of Benzyl Amines

6 Oxidations of Alcohols

7 Other Oxidative Transformations by Heteroatom-Doped Carbon Materials

8 Asphaltene Oxide

9 Conclusions and Outlook

Key words

carbocatalysis - oxidative dehydrogenation - aromatization - carbon–carbon coupling - carbon–heteroatom coupling

Full Text

References

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