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Synthesis 2023; 55(07): 1123-1129
DOI: 10.1055/a-1983-3890
DOI: 10.1055/a-1983-3890
paper
Samarium-Promoted Homocoupling of Benzaldehydes and In Situ Condensation with Esters Under the Catalysis of Cuprous Iodide
Authors
The project was sponsored by the Shandong Provincial Key Research and Development Program (SPKR&DP) (2019GGXI02036), and the Open Project of Faculty of Chemistry of Qingdao University of Science and Technology (QUSTHX201902).
Abstract
A novel C–H functionalization method was successfully explored by a reductive three molecule coupling of benzaldehydes and esters mediated by samarium and cuprous iodide; thus, the diarylmethanol skeletons were afforded readily via an in situ esterification in one-pot. Substrates including a variety of esters and different benzaldehydes were investigated, and the desired products were readily obtained in moderate to good yields under mild conditions.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1983-3890.
- Supporting Information (PDF)
Publication History
Received: 03 September 2022
Accepted after revision: 21 November 2022
Accepted Manuscript online:
21 November 2022
Article published online:
14 December 2022
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