Synthesis of β-Hydroxyhydrophosphonic Acids from Inorganic Sodium Hypophosphite

Abstract

An efficient approach to access β-hydroxyhydrophosphonic acid derivatives is reported by ring-opening reaction of readily available epoxides with green, inexpensive, and safe inorganic salt sodium hypophosphate as the phosphorus source in the presence of silver trifluoromethanesulfonate as the catalyst. The reaction is achieved under simple operation and exhibits excellent selectivity as well as good functional group compatibility.

Key words

sodium hypophosphite - β-hydroxyhydrophosphonic acid - ethylene oxide compounds

Publication History

Received: 12 June 2023

Accepted after revision: 19 July 2023

Accepted Manuscript online:
19 July 2023

Article published online:
13 September 2023

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