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Synfacts 2010(4): 0499-0499  
DOI: 10.1055/s-0029-1219456
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of Tetrazoles with Mesoporous ZnS Nanospheres

Contributor(s): Yasuhiro Uozumi, Takao Osako
L. Lang, B. Li, W. Liu, L. Jiang, Z. Xu*, G. Yin
Nanjing University, P. R. of China
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Publikationsverlauf

Publikationsdatum:
22. März 2010 (online)

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Significance

Mesoporous zinc sulfide nanospheres (MZNSS) were prepared by pyrolysis of Zn(OAc)2 and thiourea in the presence of poly­vinylpyrrolidone (PVP) (eq. 1). MZNSS catalyzed the reaction of aryl or benzyl nitriles with sodium azide to give the corresponding 5-substituted 1H-tetrazoles in 76 to >99% yield (10 examples, eq. 2).