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Synthesis 2010(24): 4282-4286
DOI: 10.1055/s-0030-1258283
DOI: 10.1055/s-0030-1258283
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New YorkTrimethylsilyl Chloride Promoted Selective Desulfurization of Thiocarbonyls to Carbonyls with Hydrogen Peroxide
Further Information
Received
23 August 2010
Publication Date:
05 October 2010 (online)
Publication History
Publication Date:
05 October 2010 (online)

Abstract
In the presence of hydrogen peroxide and trimethylsilyl chloride, thiocarbonyls desulfurize to the corresponding carbonyls. The safe, operationally simple, general reaction gives excellent yields in short reaction times with no side reactions and excellent regioselectivity, which makes this process an attractive, environmentally benign alternative for the desulfurization of thiocarbonyls.
Key words
protecting groups - thiocarbonyls - desulfurization - trimethylsilyl chloride - hydrogen peroxide
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