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Synthesis 2012; 44(20): 3185-3190
DOI: 10.1055/s-0032-1317012
DOI: 10.1055/s-0032-1317012
paper
Convenient Methods to Access Chiral Camphanyl Amine Derivatives by Sodium Borohydride Reduction of d-(–)-Camphorquinone Imines
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Further Information
Publication History
Received: 14 June 2012
Accepted after revision: 11 July 2012
Publication Date:
21 August 2012 (online)
Abstract
d-(–)-Camphorquinone imines prepared using methanolic ammonia, ethanol amine, exo-(–)-bornylamine, ethylene diamine, propylene diamine, and trans-(R,R)-1,2-diaminocyclohexane, upon reduction using sodium borohydride in methanol, give the corresponding chiral exo amino alcohol and diamine derivatives in good yields (75–95%).
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