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Synthesis 2012; 44(23): 3655-3660
DOI: 10.1055/s-0032-1317516
DOI: 10.1055/s-0032-1317516
paper
Synthesis of Nitroxide-Annulated Carbocycles and Heterocycles
Further Information
Publication History
Received: 16 August 2012
Accepted after revision: 10 October 2012
Publication Date:
30 October 2012 (online)
Dedicated to Prof. Péter Mátyus on the occasion of his 60th birthday
Abstract
New, pyrroline nitroxide annulated lactones, polycycles, and maleimide were synthesized by classical and microwave-assisted methodology. We report the application of the metathesis reaction in the presence of nitroxide yielding a pyrroline nitroxide condensed 1,4-benzoquinone as a paramagnetic dienophile. The formation of the isoselenazolone-fused pyrroline ring system was examined and different reactivity was observed with pyrrolin-1-oxyl and pyrroline derivatives.
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- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
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