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Synthesis 2015; 47(19): 2991-2996
DOI: 10.1055/s-0034-1380815
DOI: 10.1055/s-0034-1380815
paper
Switchable Copper-Catalyzed Cascade Synthesis of Thiazolidine-2-thiones and Thiazole-2(3H)-thiones
Authors
Weitere Informationen
Publikationsverlauf
Received: 06. Februar 2015
Accepted after revision: 17. April 2015
Publikationsdatum:
17. Juni 2015 (online)
Abstract
A novel copper-catalyzed cascade synthesis of thiazolidine-2-thiones from N-(2-bromoallyl)amines and carbon disulfide has been developed. The procedure combines carbamodithioic acid formation and copper-catalyzed intramolecular S-vinylation in one sequence. By elevating the temperature, the one-pot reaction efficiently affords thiazole-2(3H)-thiones in moderate to good yields.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380815.
- Supporting Information (PDF)
-
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