Recent Progress on Copper-Mediated Directing-Group-Assisted C(sp2)–H Activation

Ming Shang; Shang-Zheng Sun; Hong-Li Wang; Ming-Ming Wang; Hui-Xiong Dai

doi:10.1055/s-0035-1562795

Synthesis, Inhaltsverzeichnis

Synthesis 2016; 48(24): 4381-4399
DOI: 10.1055/s-0035-1562795

short review

Recent Progress on Copper-Mediated Directing-Group-Assisted C(sp²)–H Activation

Authors

Ming Shang

^aState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China
Shang-Zheng Sun

^bDepartment of Chemistry, Innovative Drug Research Center, Shanghai University, 99 Shangda Road, 200444, P. R. of China eMail: hxdai@sioc.ac.cn
Hong-Li Wang

^aState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China
Ming-Ming Wang

^aState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China
Hui-Xiong Dai*

^aState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China

Abstract

Alle Artikel dieser Rubrik

Abstract

Considerable progress has been made in the area of copper-mediated C(sp²)–H functionalization reactions with the assistance of chelating directing groups. Due to the advantages of copper catalysts such as low cost, low toxicity, and unique reactivity compared to precious metals, they have attracted more and more attention in organic synthesis. This review summarizes recent advances in this field according to the classification of directing groups.

1 Introduction

2 The Pyridine Directing Group

2.1 C–N Bond Formation

2.2 C–O Bond Formation

2.3 C–S Bond Formation

2.4 C–C Bond Formation

2.5 C–CN Bond Formation

2.6 C–Halogen Bond Formation

3 Bidentate Directing Groups

3.1 8-Aminoquinoline

3.2 (2-Pyridyl)Sulfonyl and Picolinic Acid

3.3 Amide-Oxazoline Auxiliary

3.4 2-(Pyridin-2-yl)isopropylamine (PIP Amine)

3.5 2-Aminopyridine 1-Oxide

4 Conclusions and Outlook

Key words

C–H bond functionalization - copper - pyridine - bidentate directing group

Volltext

Referenzen

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