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Synthesis 2017; 49(03): 539-553
DOI: 10.1055/s-0036-1588645
DOI: 10.1055/s-0036-1588645
feature
Photocaged Hydrocarbons, Aldehydes, Ketones, Enones, and Carboxylic Acids and Esters that Release by the Norrish II Cleavage Protocol and Beyond: Controlled Photoinduced Fragrance Release
Autoren
Weitere Informationen
Publikationsverlauf
Received: 13. Oktober 2016
Accepted after revision: 13. Oktober 2016
Publikationsdatum:
01. Dezember 2016 (online)
Abstract
Five families of caged fragrance compounds that allow the storage and release of the following small volatile organic molecules are described: terpene hydrocarbons, aldehydes, ketones, Michael-type α,β-unsaturated enones, and carboxylic acids and esters. These caged molecules are released by photoexcitation via carbonyl-directed hydrogen-transfer processes and subsequent C–C bond cleavage (Norrish Type II) or by didenitrogenation of diazirines.
Key words
caged molecules - photochemistry - hydrogen transfer - carbonyl compounds - dinitrogen releaseSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588645.
- Supporting Information (PDF) (opens in new window)
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