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Synthesis 2018; 50(03): 470-484
DOI: 10.1055/s-0036-1589133
DOI: 10.1055/s-0036-1589133
short review
Cyclopropyl- and Cyclobutylboronates and -silanes: A Stereoselective Approach
Authors
We thank the European Research Council (ERC-337776) and MINECO (CTQ2016-78779-R) for financial support. M.T. thanks MICINN for a RyC contract. V.M.-H. thanks UAM for a predoctoral fellowship.
Further Information
Publication History
Received: 01 September 2017
Accepted after revision: 19 October 2017
Publication Date:
14 December 2017 (online)
Abstract
Chiral cyclopropyl- and cyclobutylboronic esters and -silanes have become attractive intermediates for the preparation of functionalized small rings. This review highlights the stereoselective methods developed for their preparation, including both diastereo- and enantioselective approaches.
1 Introduction
2 Stereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes
2.1 Diastereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes
2.2 Asymmetric Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes
3 Conclusions
-
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For selected examples on C–B to C–N transformation:
For selected examples on homologation: