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Synthesis 2018; 50(19): 3825-3832
DOI: 10.1055/s-0037-1610434
DOI: 10.1055/s-0037-1610434
short review
Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons
Financial support from MINECO (RYC-2012-11749), Xunta de Galicia (ED431F 2016/006; GRC2014/032; Centro singular de investigación de Galicia accreditation 2016-2019, ED431G/09), and the European Union (European Regional Development Fund – ERDF) is gratefully acknowledged. M. F.-M. is grateful to MINECO for a Ramón y Cajal contract. E.R.-C. thanks Segundo Gil Dávila Foundation for a predoctoral grant.Further Information
Publication History
Received: 27 April 2018
Accepted after revision: 27 May 2018
Publication Date:
09 July 2018 (online)
Abstract
Synergistic bimetallic catalysis has become a very efficient tool for the selective carboboration of unsaturated hydrocarbons. This synthetic approach is based on the use of a catalytically generated boron-substituted organocopper nucleophile in a cross-coupling reaction catalyzed by a second transition metal. This way, hydrocarbons can be used as pro-nucleophiles in this type of transformations thus rendering a clean and operationally simple alternative to the traditional cross-coupling methodologies. This review provides a summary of the developments on this topic and discusses both the synthetic utility and mechanisms of these reactions.
1 Introduction
2 Carboboration of Alkenes via Synergistic Catalysis
3 Carboboration of 1,3-Dienes via Synergistic Catalysis
4 Carboboration of Alkynes via Synergistic Catalysis
5 Conclusions
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For related transformations using CuH/Pd catalysis, see:
For carbosilylation processes, see:
For other types of transformations involving synergistic catalysis, see: