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Synthesis 2019; 51(20): 3901-3907
DOI: 10.1055/s-0039-1690017
DOI: 10.1055/s-0039-1690017
paper
Construction of Esters through Sulfuryl Fluoride (SO2F2) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature
We are grateful to the National Natural Science Foundation of China (Grant No. 21772150), the Wuhan Applied Fundamental Research Plan of Wuhan Science and Technology Bureau (Grant No. 2017060201010216), the 111 Project (No. B18038) and Wuhan University of Technology for the financial support.Further Information
Publication History
Received: 06 June 2019
Accepted after revision: 11 July 2019
Publication Date:
29 July 2019 (online)
Abstract
A facile method for the construction of esters through dehydrative coupling of carboxylic acids with alcohols is developed. The reactions are mediated by sulfuryl fluoride (SO2F2) at room temperature and proceed with high efficiency. The method has several advantages including broad substrate scope, mild conditions, excellent functional group compatibility and affords high yields, even on gram scale.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690009.
- Supporting Information
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