Synthesis, Inhaltsverzeichnis Synthesis 2021; 53(01): 51-64DOI: 10.1055/s-0040-1707234 short review © Georg Thieme Verlag Stuttgart · New YorkRecent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents Autor*innen Institutsangaben José María Muñoz-Molina∗ Tomás R. Belderrain∗ Pedro J. Pérez ∗ Laboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Campus de El Carmen s/n, 21007-Huelva, Spain eMail: perez@ciqso.uhu.es Artikel empfehlen Abstract Artikel einzeln kaufen(opens in new window) Alle Artikel dieser Rubrik(opens in new window) Abstract This Short Review is aimed at giving an update in the area of copper-catalyzed C–H functionalization involving nitrogen-centered radicals generated from substrates containing N–F bonds. These processes include intermolecular Csp3–H bond functionalization, remote Csp3–H bond functionalization via intramolecular hydrogen atom transfer (HAT), and Csp2–H bond functionalization, which might be of potential use in industrial applications in the future. 1 Introduction 2 Intermolecular Csp3–H Functionalization 3 Remote Csp3–H Functionalization 4 Csp2–H Functionalization 5 Conclusion Key words Key wordscopper catalysis - C–H bond functionalization - amination - nitrogen–fluorine bond - radical fluorination Volltext Referenzen References 1a Romero KJ, Galliher MS, Pratt DA, Stephenson CR. J. Chem. Soc. Rev. 2018; 47: 7851 1b Fischer H. Chem. Rev. 2001; 101: 3581 1c Leifert D, Studer A. Angew. Chem. Int. Ed. 2020; 59: 74 1d Jasperse CP, Curran DP, Fevig TL. Chem. Rev. 1991; 91: 1237 1e Studer A, Curran DP. Angew. Chem. Int. Ed. 2016; 55: 58 2a Togo H. Advanced Free Radical Reactions for Organic Synthesis. Elsevier; Amsterdam: 2004 2b Yan M, Lo JC, Edwards JT, Baran PS. J. Am. 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