Copillar[5]arene Chemistry: Synthesis and Applications

Wenzhang Chen; Stéphane P. Vincent

doi:10.1055/s-0040-1738369

Synthesis, Table of Contents

Synthesis 2023; 55(02): 246-262
DOI: 10.1055/s-0040-1738369

short review

Special Issue dedicated to Prof. Alain Krief

Copillar[5]arene Chemistry: Synthesis and Applications

Authors

Wenzhang Chen

^aGuizhou Provincial Engineering Technology Research Center for Chemical Drug R&D, Guizhou Medical University, Guiyang, 550004, P. R. of China

^bDepartment of Chemistry, UNamur, NARILIS, Rue de Bruxelles 61, B-5000 Namur, Belgium
Stéphane P. Vincent∗

^bDepartment of Chemistry, UNamur, NARILIS, Rue de Bruxelles 61, B-5000 Namur, Belgium

Abstract

All articles of this category

Abstract

Research on pillar[n]arenes has witnessed a very quick expansion. This emerging class of functionalized macrocyclic oligoarenes not only offers host–guest properties due to the presence of the central cavity, but also presents a wide variety of covalent functionalization possibilities. This short review focuses on copillararenes, a subfamily of pillar[n]arenes. In copillararenes, at least one of the hydroquinone units bears different functional groups compared to the others. After having defined the particular features of copillararenes, this short review compares the different synthetic strategies allowing their construction. Some key applications and future perspectives are also described.

1 Introduction

2 General Features of Pillar[5]arenes

3 Synthesis of Functionalized Copillar[4+1]arenes

4 Concluding Remarks

Key words

copillararenes - supramolecular chemistry - macrocycles - host–guest compounds - phenols

Full Text

References

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