Synthesis of 1H-2-Benzopyran-5,8-dione Derivatives from 2-(1-Hydroxy­alkyl)-1,4-benzoquinones and Enamines

Kazuhiro Kobayashi; Kosaku Nomura; Toshikazu Ogata; Miyuki Tanmatsu; Osamu Morikawa; Hisatoshi Konishi

doi:10.1055/s-2003-38066

PAPER

Synthesis of 1H-2-Benzopyran-5,8-dione Derivatives from 2-(1-Hydroxyalkyl)-1,4-benzoquinones and Enamines

Kazuhiro Kobayashi*, Kosaku Nomura, Toshikazu Ogata, Miyuki Tanmatsu, Osamu Morikawa, Hisatoshi Konishi
Department of Materials Science, Faculty of Engineering, Tottori University, Koyama-minami, Tottori 680-8552, Japan
Fax: +81(857)315263; e-Mail: kkoba@chem.tottori-u.ac.jp;

Abstract

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Abstract

An efficient synthesis of the title benzopyranodione derivatives based on a Michael addition/cyclization sequence between 2-(1-hydroxyalkyl)-1,4-benzoquinones and enamines (or an imine) is described.

Key words

enamines - heterocycles - benzoquinones

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References

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Synthesis of 1H-2-Benzopyran-5,8-dione Derivatives from 2-(1-Hydroxy­alkyl)-1,4-benzoquinones and Enamines

Synthesis of 1H-2-Benzopyran-5,8-dione Derivatives from 2-(1-Hydroxyalkyl)-1,4-benzoquinones and Enamines