Transesterification/Acylation Reactions Catalyzed by Molecular Catalysts

Gabriela A. Grasa; Rohit Singh; Steven P. Nolan

doi:10.1055/s-2004-822323

REVIEW

Transesterification/Acylation Reactions Catalyzed by Molecular Catalysts

Gabriela A. Grasa^a, Rohit Singh^b, Steven P. Nolan*^b
^a Johnson Matthey Catalysts Chiral Technologies, 28 Cambridge Science Park, Milton Road, CB4 1FP, Cambridge, UK
^b Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA
Fax: +1(504)2806445; e-Mail: snolan@uno.edu;

Abstract

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Abstract

A survey of catalysts able to mediate the transesterification/acylation reaction is presented. Metal and organic catalysts are capable of facilitating this important transformation.

1 Introduction
2 Transesterification Reactions Catalyzed by Lewis Acids
2.1 Lanthanide (Sm) Catalysis
2.2 Tin Catalysis
2.3 Indium Catalysis
2.4 Yttrium Catalysis
3 Transesterification Reactions Catalyzed by Nucleophilic Catalysts
3.1 Superbase-Catalyzed Transesterification of Esters with Alcohols
3.2 Nucleophilic N-Heterocyclic Carbene (NHC) Catalysis
4 Conclusions

Key words

transesterifications - acylations - catalysis - carbenes - esters

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Referenzen

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