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Synfacts 2008(3): 0260-0260  
DOI: 10.1055/s-2008-1042715
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York

Base Photogeneration for Unzipping Depolymerization

Contributor(s): Timothy M. Swager, Jose M. Lobez
H. Yaguchi, T. Sasaki*
Tokyo University of Science, Japan
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Publikationsdatum:
21. Februar 2008 (online)

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Significance

The authors propose the syntheses of a series of poly(olefin sulfone)s containing different side chains. Upon irradiation, the side chains yield a base which thereby induces depolymeri­zation. These materials have important significance for lithography applications and as reusable (degradable) materials.