Synfacts
Issue 03 · March 2008
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Synform
A25
SYNFORM
ISSUE 2008/03
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Synthesis of Natural Products and Potential Drugs
0219
Synthesis of Quadrangularin A and Pallidol
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0220
Synthesis of (+)-Vinblastine
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0221
Synthesis of Phomopsin B
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0222
Synthesis of a Dual Serotonin Reuptake Inhibitor/Histamine H
3
Antagonist
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0223
Synthesis of an NK-1 Receptor Antagonist (CF-17,493)
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0224
Syntheses of ()-Epibatidine and ()-Epiboxidine
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0225
Synthesis of MK-0974
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0226
Synthesis of (±)-Communesin F
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0227
Synthesis of (+)-Frondosin A
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0228
Synthesis of Iejimalide B
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0229
Synthesis of ()-γ-Rubromycin
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0230
Formal Synthesis of Leucascandrolide A
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0231
Synthesis of (+)-Spirolaxine Methyl Ether
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0232
Synthesis of (-)-Batzelladine D
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0233
Synthesis of (-)-Decarbamoyloxysaxitoxin
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Synthesis of Heterocycles
0235
Synthesis of Chiral Pyridyl Alcohols by Cyclotrimerization
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0236
Copper-Catalyzed Synthesis of 2-Imino-1,2-dihydroquinolines and -thiochromenes
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0237
Copper-Catalyzed C-N Bond Coupling Approach to Highly Substituted Oxazoles
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0238
[
c
]-Annelated Pyridines via Intramolecular Diels-Alder Reaction
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0239
Ring Expansion of Tetrahydroisoquinolines to Form Benzoazocines
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0240
Double Suzuki-Miyaura Coupling in the Synthesis of Imidazo[1,2-
a
]pyridine Derivatives
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0241
Synthesis of Substituted Pyrroles from 2-Azetidinone Allenols
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0242
Synthesis of Piperidinones from β-Amino Acids by Petasis Methylenation
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0243
Polycyclic Lactams via Cu(II)-Mediated Intramolecular Alkene Carboamination
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0244
Curtius-Rearrangement Approach to 2,3-Substituted Indoles
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0245
Three-Component Synthesis of Functionalized Pyridines
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0246
Synthesis of Furans via Copper-Catalyzed [4+1] Cycloaddition
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0247
Synthesis of Imidazolines from
N
-Imidoylaziridines
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0248
In-Mediated Conversion of 2-Alkynylphenyl Isothiocyanates to Quinoline-2-thiones
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0249
Substituted Indazolobenzoxazines via One-Pot Intramolecular Bis-Heterocyclizations
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Synthesis of Materials and Unnatural Products
0251
End-Substituted Pentacenes
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0252
Sensing Hg
2+
with a Core-Modified Expanded Porphyrine
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0253
Functionalized Naphthalene Diimides
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0254
Switchable Nonlinear Optics
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0255
Molecularly Imprinted Conjugated Polymer
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0256
Responsive Nanoporous Network
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0257
Lose an Alkene and Gain a Polymer
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0258
Catalytic Silylation of Solid Surfaces at Room Temperature
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0259
Nanotweezers for Chiral Discrimination of Carbon Nanotubes
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0260
Base Photogeneration for Unzipping Depolymerization
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0261
Macrocyclic Allenes
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0262
Excellent Blue Fluorescent Trispirobifluorenes
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0263
Shortcut to a 42-Membered Trianglimine Macrocycle
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0265
Application of DYKAT to Au(I)-Catalyzed Hydroamination of Allenes
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0266
Synthesis of
E
-α,β-Unsaturated Esters via Hydration of Propargylic Acetates
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0267
Catalytic Asymmetric Allylic Alkylation with Vinylaluminum Reagents
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0268
Diels-Alder Reaction in Ionic Liquids: Remarkable Reactivity and Selectivity
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0269
Asymmetric Ruthenium-Mediated Propargylation of Indoles
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0270
Palladium-Catalyzed Arylation of Silylphosphines
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0271
Effect of the Double Bond Geometry on the Enantioselectivity of ACA
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0272
1,2,3-Trisubstituted Indanes via Tandem Conjugate Additions
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0273
Chiral Macrocyclic Ytterbium Complex Catalysis in Aqueous Media
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0274
Synthesis of
C
-2 Methylene Glycosides by AuCl
3
Catalysis
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0275
Rhodium-Catalyzed Conjugate Addition of Boronic Acids to Vinyl 2-Pyridyl Sulfones
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0276
Asymmetric Desymmetrization and Kinetic Resolution of 1,2-Diols
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0277
TRISPHAT-N Anion Provides Bench-Stable Ruthenium Catalyst
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0278
Nd/Na-Catalyzed
Anti
-Selective Nitroaldol Reaction
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0279
Synthesis of Acyl Aminocyclopentenes with Acyl Anion Nucleophiles
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0280
Diastereoselective Cascade Reactions: Cyclization-Cross-Coupling
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0281
Stereoselective Synthesis of α-Substituted
Z
-Homoallylic Alcohols
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0282
Addition of Arylboronic Acids to
N
-Boc Imines Generated in situ
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0283
Catalytic Nucleophilic Ring Closure ofπ-Allylpalladium Intermediates
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0284
Novel Self-Assembled Titanium Catalyst for Asymmetric Cyanoethoxycarbonylation
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0285
Enantioselective Aldol Synthesis via Radical Addition to Cyclic Enones
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0286
Cyclopropanation by Rhenium(I) Bi- and Terpyridine Tricarbonyl Complexes
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0287
Boron-Based Reagent for Enantioselective Reduction of Ketones
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0288
Nickel-Catalyzed Regioselective Olefin-Directed Cross-Coupling Reaction
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0289
Rhodium-Catalyzed Asymmetric Transfer Hydrogenations
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0290
Asymmetric Lithiation of 2-Alkynyl Aryl Sulfides
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Metal-Mediated Synthesis
0291
Nickel-Catalyzed Coupling of α-Halocarbonyl Compounds with Arylboronic Acids
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0292
Simple and Universal Pd(II) Precatalyst for the Suzuki-Miyaura Cross-Couplings
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0293
Reverse Prenylation, Crotylation and Allylation of Alcohols and Aldehydes via Transfer Hydrogenation
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0294
Imines and Pyrrolidines via Metal-Free Oxidation of Sulfonamides by Iodine(III)
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0295
Convenient and General Iron-Catalyzed Hydrosilylation of Aldehydes
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0296
In(0)/Cu(I)-Mediated Alkylation of Imines in Aqueous Media
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0297
In(III)-Catalyzed Radical Addition of Alkyl and Aryl Iodides to Acrylates
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0298
ortho
Cupration via Direct Hydrogen-Copper Exchange
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0299
Multicomponent One-Pot Synthesis of Aminals and Thioaminals
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0300
ortho
-Selective Cross-Coupling of Dichlorobenzenes with Grignard Reagents
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0301
Regio- and Stereoselective Synthesis of 1,4-Dienes
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0302
Direct Aminoalkylation via Nickel-Catalyzed Negishi Cross-Coupling Reactions
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0303
An Improved Catalyst System for Ullmann-Type Couplings between Alcohols and Aryl Halides
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0304
Mixed Lithium-Zinc Species for the Deprotonation of Five-Membered Aromatic Heterocycles
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Organo- and Biocatalysis
0305
Deracemization through Concurrent Oxidation and Reduction
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0306
ACDC-Epoxidation
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0307
NHC-Catalyzed β-Lactam Synthesis
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0308
NHC-Catalyzed Staudinger Reaction
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0309
Organocatalytic Oxy-Michael Addition
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0310
Polymer-Supported Hantzsch Ester as An Efficient Hydrogen Source
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0311
Reaction Control by Catalyst Design: 1,2- versus 1,4-Addition
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0312
Organocatalytic Tandem Oxidative Dearomatization-Michael Reaction
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0313
α-Vinylation of Aldehydes
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0314
Metal-Free Reduction of Tertiary Amides
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Polymer-Supported Synthesis
0315
Traceless Solid-Phase Preparation of Thiomorpholin-3-ones
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0316
An Efficient Copper Nanoparticle Catalytic System for C-S Bond Formation
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0317
Oxidation of Alcohols Using Hydrotalcite-Supported Silver Nanoparticles
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0318
Aerobic Oxidation of Alcohols with CHP-Supported Ruthenium Species
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0319
Silica-Supported Rhodium Catalyst for Hydrosilylation of Alkenes
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0320
Silica-Supported Palladium Catalysts for Aldol Reaction
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0321
Oxidation of Sulfides with SBA-15-Supported Tungsten Oxide Nanocluster
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0322
Magnetically Recoverable Palladium Catalyst
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0323
Solid-Phase Synthesis of Diverse α,β-Unsaturated Carbonyl Compounds
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0324
Solid-Phase Synthesis of
N
-Aminodipeptides in High Optical Purity
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0325
Hartwig-Buchwald Amination on Solid Supports
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0326
Superior Liquid-Uptake Resins for Polymer-Supported Synthesis (SLURPS)
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0327
Cycloaddition of Epoxide and CO
2
with PEG-Supported Guanidinium Catalyst
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