Synfacts

Issue 03 · March 2008

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A25
SYNFORM ISSUE 2008/03 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
0219
Synthesis of Quadrangularin A and Pallidol FREE ACCESS

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0220
Synthesis of (+)-Vinblastine

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0221
Synthesis of Phomopsin B

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0222
Synthesis of a Dual Serotonin Reuptake Inhibitor/Histamine H₃ Antagonist

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0223
Synthesis of an NK-1 Receptor Antagonist (CF-17,493)

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0224
Syntheses of ()-Epibatidine and ()-Epiboxidine

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0225
Synthesis of MK-0974

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0226
Synthesis of (±)-Communesin F

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0227
Synthesis of (+)-Frondosin A

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0228
Synthesis of Iejimalide B

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0229
Synthesis of ()-γ-Rubromycin

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0230
Formal Synthesis of Leucascandrolide A

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0231
Synthesis of (+)-Spirolaxine Methyl Ether

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0232
Synthesis of (-)-Batzelladine D

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0233
Synthesis of (-)-Decarbamoyloxysaxitoxin

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Synthesis of Heterocycles
0235
Synthesis of Chiral Pyridyl Alcohols by Cyclotrimerization

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0236
Copper-Catalyzed Synthesis of 2-Imino-1,2-dihydroquinolines and -thiochromenes

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0237
Copper-Catalyzed C-N Bond Coupling Approach to Highly Substituted Oxazoles

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0238
[c]-Annelated Pyridines via Intramolecular Diels-Alder Reaction

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0239
Ring Expansion of Tetrahydroisoquinolines to Form Benzoazocines

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0240
Double Suzuki-Miyaura Coupling in the Synthesis of Imidazo[1,2-a]pyridine Derivatives

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0241
Synthesis of Substituted Pyrroles from 2-Azetidinone Allenols

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0242
Synthesis of Piperidinones from β-Amino Acids by Petasis Methylenation

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0243
Polycyclic Lactams via Cu(II)-Mediated Intramolecular Alkene Carboamination

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0244
Curtius-Rearrangement Approach to 2,3-Substituted Indoles

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0245
Three-Component Synthesis of Functionalized Pyridines

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0246
Synthesis of Furans via Copper-Catalyzed [4+1] Cycloaddition

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0247
Synthesis of Imidazolines from N-Imidoylaziridines

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0248
In-Mediated Conversion of 2-Alkynylphenyl Isothiocyanates to Quinoline-2-thiones

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0249
Substituted Indazolobenzoxazines via One-Pot Intramolecular Bis-Heterocyclizations

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Synthesis of Materials and Unnatural Products
0251
End-Substituted Pentacenes

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0252
Sensing Hg²⁺ with a Core-Modified Expanded Porphyrine

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0253
Functionalized Naphthalene Diimides

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0254
Switchable Nonlinear Optics

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0255
Molecularly Imprinted Conjugated Polymer

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0256
Responsive Nanoporous Network

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0257
Lose an Alkene and Gain a Polymer

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0258
Catalytic Silylation of Solid Surfaces at Room Temperature

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0259
Nanotweezers for Chiral Discrimination of Carbon Nanotubes

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0260
Base Photogeneration for Unzipping Depolymerization

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0261
Macrocyclic Allenes

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0262
Excellent Blue Fluorescent Trispirobifluorenes

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0263
Shortcut to a 42-Membered Trianglimine Macrocycle

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0265
Application of DYKAT to Au(I)-Catalyzed Hydroamination of Allenes

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0266
Synthesis of E-α,β-Unsaturated Esters via Hydration of Propargylic Acetates

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0267
Catalytic Asymmetric Allylic Alkylation with Vinylaluminum Reagents FREE ACCESS

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0268
Diels-Alder Reaction in Ionic Liquids: Remarkable Reactivity and Selectivity

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0269
Asymmetric Ruthenium-Mediated Propargylation of Indoles

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0270
Palladium-Catalyzed Arylation of Silylphosphines

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0271
Effect of the Double Bond Geometry on the Enantioselectivity of ACA

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0272
1,2,3-Trisubstituted Indanes via Tandem Conjugate Additions

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0273
Chiral Macrocyclic Ytterbium Complex Catalysis in Aqueous Media

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0274
Synthesis of C-2 Methylene Glycosides by AuCl₃ Catalysis

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0275
Rhodium-Catalyzed Conjugate Addition of Boronic Acids to Vinyl 2-Pyridyl Sulfones

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0276
Asymmetric Desymmetrization and Kinetic Resolution of 1,2-Diols

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0277
TRISPHAT-N Anion Provides Bench-Stable Ruthenium Catalyst

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0278
Nd/Na-Catalyzed Anti-Selective Nitroaldol Reaction

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0279
Synthesis of Acyl Aminocyclopentenes with Acyl Anion Nucleophiles

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0280
Diastereoselective Cascade Reactions: Cyclization-Cross-Coupling

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0281
Stereoselective Synthesis of α-Substituted Z-Homoallylic Alcohols

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0282
Addition of Arylboronic Acids to N-Boc Imines Generated in situ

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0283
Catalytic Nucleophilic Ring Closure ofπ-Allylpalladium Intermediates

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0284
Novel Self-Assembled Titanium Catalyst for Asymmetric Cyanoethoxycarbonylation

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0285
Enantioselective Aldol Synthesis via Radical Addition to Cyclic Enones

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0286
Cyclopropanation by Rhenium(I) Bi- and Terpyridine Tricarbonyl Complexes

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0287
Boron-Based Reagent for Enantioselective Reduction of Ketones

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0288
Nickel-Catalyzed Regioselective Olefin-Directed Cross-Coupling Reaction

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0289
Rhodium-Catalyzed Asymmetric Transfer Hydrogenations

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0290
Asymmetric Lithiation of 2-Alkynyl Aryl Sulfides

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Metal-Mediated Synthesis
0291
Nickel-Catalyzed Coupling of α-Halocarbonyl Compounds with Arylboronic Acids FREE ACCESS

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0292
Simple and Universal Pd(II) Precatalyst for the Suzuki-Miyaura Cross-Couplings

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0293
Reverse Prenylation, Crotylation and Allylation of Alcohols and Aldehydes via Transfer Hydrogenation

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0294
Imines and Pyrrolidines via Metal-Free Oxidation of Sulfonamides by Iodine(III)

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0295
Convenient and General Iron-Catalyzed Hydrosilylation of Aldehydes

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0296
In(0)/Cu(I)-Mediated Alkylation of Imines in Aqueous Media

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0297
In(III)-Catalyzed Radical Addition of Alkyl and Aryl Iodides to Acrylates

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0298
ortho Cupration via Direct Hydrogen-Copper Exchange

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0299
Multicomponent One-Pot Synthesis of Aminals and Thioaminals

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0300
ortho-Selective Cross-Coupling of Dichlorobenzenes with Grignard Reagents

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0301
Regio- and Stereoselective Synthesis of 1,4-Dienes

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0302
Direct Aminoalkylation via Nickel-Catalyzed Negishi Cross-Coupling Reactions

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0303
An Improved Catalyst System for Ullmann-Type Couplings between Alcohols and Aryl Halides

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0304
Mixed Lithium-Zinc Species for the Deprotonation of Five-Membered Aromatic Heterocycles

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Organo- and Biocatalysis
0305
Deracemization through Concurrent Oxidation and Reduction FREE ACCESS

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0306
ACDC-Epoxidation

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0307
NHC-Catalyzed β-Lactam Synthesis

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0308
NHC-Catalyzed Staudinger Reaction

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0309
Organocatalytic Oxy-Michael Addition

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0310
Polymer-Supported Hantzsch Ester as An Efficient Hydrogen Source

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0311
Reaction Control by Catalyst Design: 1,2- versus 1,4-Addition

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0312
Organocatalytic Tandem Oxidative Dearomatization-Michael Reaction

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0313
α-Vinylation of Aldehydes

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0314
Metal-Free Reduction of Tertiary Amides

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Polymer-Supported Synthesis
0315
Traceless Solid-Phase Preparation of Thiomorpholin-3-ones

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0316
An Efficient Copper Nanoparticle Catalytic System for C-S Bond Formation

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0317
Oxidation of Alcohols Using Hydrotalcite-Supported Silver Nanoparticles FREE ACCESS

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0318
Aerobic Oxidation of Alcohols with CHP-Supported Ruthenium Species

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0319
Silica-Supported Rhodium Catalyst for Hydrosilylation of Alkenes

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0320
Silica-Supported Palladium Catalysts for Aldol Reaction

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0321
Oxidation of Sulfides with SBA-15-Supported Tungsten Oxide Nanocluster

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0322
Magnetically Recoverable Palladium Catalyst

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0323
Solid-Phase Synthesis of Diverse α,β-Unsaturated Carbonyl Compounds

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0324
Solid-Phase Synthesis of N-Aminodipeptides in High Optical Purity

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0325
Hartwig-Buchwald Amination on Solid Supports

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0326
Superior Liquid-Uptake Resins for Polymer-Supported Synthesis (SLURPS)

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0327
Cycloaddition of Epoxide and CO₂ with PEG-Supported Guanidinium Catalyst

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