Synfacts

Issue 10 · October 2008

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A93
SYNFORM ISSUE 2008/09 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
1009
Synthesis of Callipeltoside C FREE ACCESS

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1010
Synthesis of Lobotoside E

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1011
Synthesis of (-)-Clavosolide D

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1012
Synthesis of JNJ-26076713

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1013
Synthesis of (+)-Oocydin A

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1014
Synthesis of (+)-Brefeldin A

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1015
Synthesis of Ethyl Deoxymonate B

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1016
Synthesis of (-)-Octalactin A

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1017
Synthesis of 7-Epi (+)-FR900482

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1018
A Synthesis of Callipeltoside A

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1019
Synthesis of GE2270 A

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1020
Synthesis of ent-Lepadin F

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1021
Synthesis of (+)-Neopeltolide

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1022
Synthesis of Palmerolide A

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1023
Synthesis of ()-Stemonamine

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Synthesis of Heterocycles
1025
Synthesis of N-Substituted Pyrido[b]-Anellated Azaphospholes

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1026
Synthesis of Piperidinones via a Multicomponent Condensation

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1027
Synthesis of Azaheterocycles by Microwave-Assisted Activation of N-Acylarylamines

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1028
Radical-Mediated Cyclization of Thiobenzamides into Benzothiazoles

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1029
Synthesis of Pyrrolidines by a Three-Component Reaction

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1030
Synthesis of Azepines by a Gold-Catalyzed [4+3] Annulation

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1031
Synthesis of Pyrroles and Pyridines by Cyclization of N-Propargylic β-Enaminones

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1032
Cu-Catalyzed Domino Synthesis of Indolines

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1033
Aza-Nazarov Synthesis of 2H-Pyrroles

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1034
Synthesis of Polyfluoroalkylquinolines by Pd-Catalyzed Heteroannulation

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1035
3-Aminooxindoles via Microwave-Assisted Intramolecular Arylation

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1036
One-Pot Oxidative Heteroannulations to 5-Aminocoumaran Derivatives

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1037
Synthesis of Benzopyridyloxepines Contain-
ing Stereodefined Exocyclic Double Bonds

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1038
Synthesis of Caprolactams from Cyclic Imines by Cross-Metathesis

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1039
Synthesis of Polysubstituted Piperidines by Diels-Alder Reaction of N-Alkenyl Iminiums FREE ACCESS

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Synthesis of Materials and Unnatural Products
1041
A Spin-Quintet Tetraradical

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1042
A Zwitterionic Ladder

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1043
Hyperbranched Poly(fluorenevinylenes)s

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1044
Rapidly Switching Photochromic Dyes FREE ACCESS

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1045
Big, Flat Molecules

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1046
Photoconductive Liquid Crystalline Oligothiophene-C₆₀ Dyads

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1047
One-Pot Synthesis of Tetraiodinated Di(perylene bisimide)

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1048
Organomercury-Induced Fluorogenic Unmasking for Biological Sensing

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1049
Substituted Anthracenes

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1050
Selective Insertion Polymerization

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1051
TriazaTMM Triplet Diradical

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1052
A [2]Catenane with Speed Bumps

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1053
Very Rigid Porphyrin Prisms

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
1055
Enantioselective Diamination of Terminal Olefins

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1056
Kinugasa Reaction Applied to the Synthesis of α-Amino-β-lactams

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1057
Double Catalytic Enantioselective Alkylation: Total Synthesis of (-)-Cyanthiwigin F FREE ACCESS

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1058
Aluminum Salen Contact Ion Pair Catalyzed Synthesis of β-Lactones

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1059
Asymmetric Allylic C-H Oxidation of Terminal Olefins

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1060
Enantioselective Ruthenium-Catalyzed Allenylidene-Ene Cyclization

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1061
New Ligands for Copper-Catalyzed Friedel-Crafts Reactions of Indoles

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1062
Rhodium-Catalyzed Intermolecular [4+2] Annulation of Cyclic Carbonyl Compounds

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1063
Rhodium-Catalyzed Intermolecular [4+2] Annulation of Acyl Phosphonates

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1064
Rhodium-Mediated [3,3]-Sulfonium Ylide Rearrangement of Indoles

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1065
Enantioselective Oxidative Cation/Olefin Cyclization of Polyenes

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1066
Diastereoselective Pd-Catalyzed Oxidative Cyclization of Enynes

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1067
Novel Dirhodium Catalyst for Enantio-selective C-H Amination

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1068
Titanium-Mediated Catalytic Enantioselective Ketone Arylation

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1069
Enantioselective Intermolecular 1,3-Dipolar Cycloaddition

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1070
Iridium-Catalyzed Enantioselective Hydro-genation of α,β-Unsaturated Carboxylic Acids

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1071
Double Michael Addition-Cyclization of 2,3-Allenoates with Dialkylzinc

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1072
Diastereoselective Cyclization/Borylation of Enediynes

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1073
Platinum-Catalyzed Intramolecular Vinylthiolation and Vinylselenation

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1074
Zinc-Catalyzed Cross-Coupling of Triflates with Grignard Reagents

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1075
Enantioselective Pd-Catalyzed α-Amination of α-Cyanoketones

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1076
Sulfonyldiamine-Cu Complex Catalyzed Asymmetric Henry Reaction

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1077
Aluminum-Catalyzed Addition of Phosphites to Aldehydes and Aldimines

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1078
Diastereoselective Addition of Allylzinc Reagents to Sulfinimines

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1079
Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides and Alkenes

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1080
Branch-Selective Hydroformylation by Rh-Scaffolding Ligand Complexes

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1081
Catalytic Enantioselective Conjugate Additions with N,N,P-Tridentate Ligands

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Metal-Mediated Synthesis
1083
CuCl-NHC-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

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1084
Zn-Catalyzed Cycloisomerizations in the Synthesis of Substituted Furans

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1085
Cross-Coupling of Secondary Alkyltrifluoroborates with Aryl Chlorides FREE ACCESS

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1086
FeBr₂-Catalyzed Synthesis of Benzimidazoles from Aryl Azides

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1087
Pd-Mediated Fluorination of Arylboronic Acids

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1088
Indoline Synthesis via a C-H Insertion-Carbopalladation-Cyclization Sequence

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1089
Stereo- and Regiospecific Synthesis of Vinyl Sulfides

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1090
Cu-Catalyzed Pd-Free Sonogashira-Type Reactions

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1091
Mn-Catalyzed Benzene Synthesis from
1,3-Dicarbonyls and Acetylenes

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1092
Ti-Mediated Synthesis of Alkenylcyclo-propanes from Dichlorocyclopropanes

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1093
Pd-Catalyzed Borylation of Aryl Halides Using Pinacol Borane

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1094
Dehydrogenative Cyclocondensation of Aldehydes, Alkynes and Dialkylsilanes

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1095
Catalytic Hydrochlorination of Unactivated Olefins

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1096
N- and C-Arylations of Oxindoles: Orthogonal Selectivity of Pd and Cu Catalysts

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1097
In-Mediated Synthesis of Allenic Esters and their Cyclization to 2-Naphthoates

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Organo- and Biocatalysis
1099
Intermolecular Stetter Reaction by NHC Catalysis

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1100
Structure-Selectivity Relationship of a Peptide Catalyst

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1101
Stereoselective Aziridine Alkylation Reactions

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1102
Asymmetric Synthesis of Tricyclic Benzopyrones

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1103
Multisubstituted Cyclopentanes by the Domino Michael-Henry Reaction

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1104
Proline Ionic Liquid in Asymmetric Michael Additions

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1105
Chiral Ammonium Betaines as Bifunctional Organocatalysts FREE ACCESS

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1106
Enantioselective Additions to Oxocarbenium Ions via Anion Binding

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1107
Chiral Information from the Solvent

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Polymer-Supported Synthesis
1109
Aerobic Oxidation of Alcohols with Carbon-Supported Pt Catalyst

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1110
Solid-Phase Fluorescent Labeling of Receptor Ligands by Click Reaction

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1111
Dehydrogenative Silylation of Primary Alcohols Catalyzed by [Au]-SMAP-Rh FREE ACCESS

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1112
Selective Debenzylation of Aryl Benzyl Ethers

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1113
Mono-Acylation of Diamine via Ionic Immobilization

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1114
Ti-Catalyzed Allylation of Aldehydes Promoted by Silica-Supported BINOL

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1115
Purification of Basic Compounds with Functionalized Silica Gel

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1116
Microwave-Assisted Synthesis of Benzimidazoles from Resin-Bound Esters

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1117
Oxidation of Sulfides with Polymer-Supported Oxo-Vanadium Catalyst

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1118
Preparation of Rhodium Nanoparticles within AISBA-15

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1119
Suzuki-Miyaura Coupling with a Magnetic Nanoparticle Supported Pd Complex

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1120
Solid-Phase Conversion of Aromatic Acetylenes to Carbonyl Compounds

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1121
[3+2] Cycloaddition Catalyzed by Cu(I)-Zeolites

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1122
Molybdenum Oxide-Catalyzed Benzylation

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Addenda and Errata
1123
1,3-Diketones via Rh-Catalyzed Reductive Acylation of Enones

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1123
Fe-Catalyzed Cross-Coupling of Dienol Phosphates with Grignard Reagents

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