Synfacts

Issue 03 · March 2006

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Synthesis of Natural Products and Potential Drugs
0185
Synthesis of Isoedunol and β-Araneosene

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0186
Synthesis of (-)-Oleocanthal

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0187
Synthesis of Eupomatilone-6

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0188
Synthesis of an Apical Sodium-Codependent Bile Acid Transporter Inhibitor

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0189
Synthesis of Tremulenediol A and Tremulenolide A

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0190
Synthesis of (+)-Amphidinolide A

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0191
Synthesis of Clavolonine

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0192
Synthesis of rac-Garsubellin A

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0193
Synthesis of Interiotherin A

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0194
Synthesis of (-)-Vindoline

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0195
Synthesis of Abyssomycin C

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0196
Synthesis of (-)-Colombiasin A and(-)-Elisapterosin B

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0197
Synthesis of mGluR2/3 Agonists

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0198
Synthesis of (±)-Taiwanianquinol B

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0199
Synthesis of (-)-Kainic Acid

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Synthesis of Heterocycles
0201
Synthesis of Pyrrolidinyl, Pyrazolidinyl, and Isoxazolidinyl Isoquinolines

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0202
Synthesis of Isoquinolines by Nickel-Catalyzed Heteroannulation

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0203
Regioselective Metallative Functionalization of 5-Azaindole

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0204
Synthesis of Polysubstituted Pyrroles via Dihydro-1,2-oxazines

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0205
Synthesis of α-Carbolines

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0206
Tetraazapentalenes: Formation and Rearrangement

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0207
Synthesis of Complex Condensed Heterocycles by Diels-Alder Reactions

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0208
Multi-Component Synthesis of 5H-Furoisoindole and Pyrrolo[3,4-f]indole Derivatives

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0209
Synthesis of Pyridazines by a Diels-Alder Strategy

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0210
Bridged Azabicycles by Ring-Closing Metathesis

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0211
Synthesis of 1H-Furo- and Pyrrolo[3,4-c]pyrrole Derivatives by Multicomponent Reactions

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0212
Synthesis of Imidazoles by Pd- and Cu-Catalyzed C-N Bond Formation

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0213
Synthesis of P-Stereogenic Oxaphosphacyclohexene-1-oxides by Ring-Closing Metathesis

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0214
2,3-Disubstituted Indoles by Stille Cross- Coupling Reaction

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0215
Synthesis of Indolizines as Illustrated in Alkaloid Construction

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Synthesis of Materials and Unnatural Products
0217
Covalent Template Approach to Macrocycle Synthesis

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0218
Synthetic Anion-Binding Macrocyclic Heterocycles

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0219
Achieving White Light Emission from an Organic Polymer

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0220
Ionic Heterocalixarenes

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0221
Coronene Derivatives via a Benzannulation Protocol

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0222
Heteroacenes for Organic Electronics

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0223
Making a Faster Molecular Rotor

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0224
Unveiling Reactive Groups Through Equilibrium Dynamics

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0225
Facile Synthesis of Bifunctional Dendritic Block Copolymers

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0226
Star-Shaped Hexa-peri-hexabenzocoronene ”Heptamer”: Synthesis and Self-Assembly

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0227
Selective and Efficient Detection of Hg²⁺ Ions in Aqueous Media

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0228
Synthesis of Polycyclic Aromatics by Annulation of Arynes with 2-Halobiaryls

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0229
Ruthenium-Catalyzed Alternating ROMP Polymerizations

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0230
One-Pot Synthesis of Helical Polyaryls

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0231
Porous, Crystalline, Covalent Organic Frameworks

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0232
Claisen-Schmidt Reaction in a Microfluidic Chip Reactor

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0233
Spherical Particles by Metal-Organic Coordination

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0235
Asymmetric C-H Activation of a Benzyl Silyl Ethers

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0236
Palladium-Catalyzed Asymmetric Amination of 2,3-Allenyl Phosphates

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0237
Ring Opening of Isoprene Monoxide with Nitrogen Nucleophiles

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0238
Asymmetric Intramolecular Cyclopropanation towards Fused Cyclopropyllactones

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0239
Rhodium-Catalyzed Intramolecular [4+2] Cycloadditions of Alkynyl Halides

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0240
Catalytic Asymmetric Nozaki-Hiyama Allenylation

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0241
Palladium-Catalyzed Asymmetric Allylic
α-Alkylation of Acyclic Ketones

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0242
Diastereoselective Synthesis of Vinylaziridenes

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0243
Dual Catalytic Decarbonylation/Asymmetric Pauson-Khand-Type Reaction

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0244
Catalytic Asymmetric Claisen Rearrangement

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0245
Asymmetric Propargylic Substitution

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0246
Asymmetric Aza-Mannich Reactions of Sulfinimines

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0247
Air- and Water-Stable Ligands for Asymmetric Hydrogenations

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0248
Diastereoselective Addition of Propargylic Copper Oxazolidinones to Aldehydes

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0249
Cyclopropane α-Amino Acids via Catalytic Asymmetric Cyclopropanation of Alkenes

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0250
Three-Component, One-pot Procedure for α-Chiral Amine Synthesis

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0251
Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates

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0252
Rh-PNP Pincer Ligand Complex Catalyzed Alkyne Dimerization

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0253
Enantioselective Diphenylzinc Addition to Various Aldehydes

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0254
Enantioselective Michael Addition of Anilines to α,β-Unsaturated N-Imides

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0255
Enantioselective Alkylative Ring Opening of Heterobicyclic Alkenes via Fesulphos Ligands

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0256
Catalytic Enantioselective Conia-Ene Reaction

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0257
Palladium-Catalyzed Stereoselective Allylic Alkylation of Lithium Enolates

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Metal-Mediated Synthesis
0259
Zn-Catalyzed Asymmetric Alkynylation of Unsaturated Aldehydes

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0260
Magnesium Bromide-Promoted Room-Temperature Cannizzaro Reaction

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0261
Air-Assisted Oxidative Coupling of Grignard Reagents with Olefins

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0262
Synthesis of Aryl Ketones from Grignard Reagents

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0263
Cu-Catalyzed Electrophilic Amination of Organozinc Compounds

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0264
Me₂Zn-Air-Mediated Radical Addition of Primary Alkyls to Imines

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0265
Arylmagnesiation of Alkynes Catalyzed by Iron and Copper Complexes

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0266
Addition of Arylboronic Acids to Azo Compounds

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0267
Ni-Catalyzed Cross-Coupling Reaction under Ni/Mg Bimetallic Cooperation

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0268
Soluble LnCl₃·2LiCl for the Improved 1,2-Addition of Grignard Reagents

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0269
CuI-Catalyzed Coupling of Aryl Iodides with Pinacolborane

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0270
Formation and Reactions of Alkylzinc Reagents in Ionic Liquids

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0271
In-Mediated One-Pot Reaction of Anilines, Enol Ethers and Allylic Bromides

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Organo- and Biocatalysis
0273
Organocatalytic Synthesis of Sphingoids

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0274
Highly Diastereo- and Enantioselective Direct Aldol Reactions in Water

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0275
Intramolecular β-Alkylation of Michael Acceptors

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0276
Organocatalytic Asymmetric Nitro-Michael Reaction

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0277
Organocatalytic Mukaiyama Aldehyde Cross-Aldol Reactions

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0278
Conjugate Addition of α-Substitutedβ-Ketoesters to α,β-Unsaturated Ketones

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0279
Phosphoric Acid Catalyzed Enantioselective Reductive Amination

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0280
Organocatalytic Direct Asymmetric Aldol Reactions in Water

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0281
Organocatalyzed Asymmetric Friedel-Crafts Amination of 2-Naphthols

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0282
Enantioselective Nitroaldol Reaction of α-Keto-esters Catalyzed by Cinchona Alkaloids

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0283
Intramolecular Crossed-Benzoin Reactions Catalyzed by Chiral Triazolium Salts

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Polymer-Supported Synthesis
0285
Solid-Phase Synthesis of Callipeltin D

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0286
Reversible Microencapsulation of Pybox-Ru Catalysts

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0287
SPOS of Olefin-Containing Peptides Using the Horner-Emmons Reaction

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0288
Synthesis of 3,5-Disubstituted 1,2,4-Triazoles on PEG6000

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0289
A High-Swelling Reagent Scaffold Suitable for Use in Aqueous and Organic Solvents

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0290
Microemulsion-Templated Synthesis of Carbon Nanotube-Supported Nanoparticles

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0291
Polar PS-Supported Phosphine Catalysts for the Aza-Morita-Baylis-Hillman Reaction

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0292
Asymmetric Arylation of Aldehydes with Polymer-Supported Amino Alcohols

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0293
Polytetrahydrofuran-Grafted Polystyrene Resin Supports for Organic Synthesis

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0294
Reusable Titanocene Cross-Linked Polymer Catalyst

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0295
Polymer-Supported Chiral Oxazaborolidinone

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0296
Polymeric Palladium Catalyst for Cross-Coupling Reactions in Water

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0297
Hydrogenation Reactions Utilizing Capillary Column Reactors

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0298
Solid-Phase Synthesis of a Spiro[5.5]ketal

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