Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C–O Bond Formation

Abstract

We report herein recent advances made by our group and others in the field of oxygen-centered radicals generated under photocatalysis. Thanks to the design of new O-radical precursors, these radicals can now be efficiently trapped by unsaturated systems in an intermolecular manner, via the formation of a new C–O bond.

1 Introduction

2 Reactions Involving Carbonyloxy Radicals

3 Reactions Involving Fluoroalkoxy Radicals

4 Reactions Involving Alkoxy Radicals

5 Conclusion

Key words

radicals - carbonyloxy - fluoroalkoxy - alkoxy - photoredox catalysis - C–O bonds

Publication History

Received: 19 June 2023

Accepted after revision: 17 July 2023

Accepted Manuscript online:
18 July 2023

Article published online:
14 September 2023

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