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Synthesis 1987; 1987(1): 62-64
DOI: 10.1055/s-1987-27846
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Synthesis of Dimethyl (1-Nitromethylalkyl)phosphonates and their Conversion to Dimethyl (1-Formylalkyl)phosphonates by Oxidation with Ozone

Mitsuji Yamashita* , Motoyuki Sugiura, Tatsuo Oshikawa, Saburo Inokawa
  • *Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, Hamamatsu 432, Japan
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Publication Date:
20 August 2002 (online)

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The addition reaction of dimethyl phosphonate to nitroalkenes gives dimethyl (1-nitromethylalkyl)-phosphonates, which are successfully converted to dimethyl (1-formylalkyl)phosphonates by oxidation with ozone.

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