Pyrimidine-5-carbonitriles from Methyl N-(Aminocarbonyl)- or N-(Aminothiocarbonyl)-imidates

Jiří Krechl; Miguel A. Pérez; Francisco J. Cuadrado; José L. Soto

doi:10.1055/s-1988-27485

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Synthesis 1988; 1988(2): 122-124
DOI: 10.1055/s-1988-27485

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Pyrimidine-5-carbonitriles from Methyl N-(Aminocarbonyl)- or N-(Aminothiocarbonyl)-imidates

Jiří Krechl^* , Miguel A. Pérez, Francisco J. Cuadrado, José L. Soto

^*Department of Organic Chemistry, Prague Institut of Chemical Technology , Suchbatarova 5, CS-166 28 Prague 6, Czechoslovakia

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Publication Date:
20 August 2002 (online)

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A number of substituted pyrimidine-5-carbonitriles and ethyl pyrimidine-5-carboxylates are prepared by reaction of methyl N-(aminocarbonyl)- or N-(aminothiocarbonyl)imidates with malononitrile, methyl cyanoacetate, or diethyl malonate.