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Synlett 1991; 1991(9): 645-646
DOI: 10.1055/s-1991-20826
DOI: 10.1055/s-1991-20826
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Enantiocontrolled Total Synthesis of Conduritols:1 (+)-Conduritol E and (-)-Conduritol F
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Publikationsverlauf
Publikationsdatum:
07. März 2002 (online)
Conduritols (+)-E, and (-)-F have been synthesized from bromobenzene in an efficient and enantiocontrolled fashion. Microbial oxidation of bromobenzene affords diene diol 2 [(1S,2S)-3-bromo-3,5-cyclohexadiene-1,2-diol] possessing the requisite cis-diol moiety of the above conduritols. Complete stereocontrol in the introduction of subsequent hydroxyls has been achieved.