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Synthesis 1991; 1991(11): 954-958
DOI: 10.1055/s-1991-28531
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A Mild Approach to N-Acylformamidines and C-Acylamidines by the Facile Reduction of Carbodiimides with Pentacoordinated Silicon Hydrides

Robert  * , J. P. Corriu, Gérard F. Lanneau, Myriam Perrot-Petta
  • *Laboratoire Hétérochimie et Amino-Acides, associé au CNRS no 1097, Université des Sciences et Techiques du Languedoc Case 007, Place Eugène Bataillon, F-34095 Montpellier Cedex 05, France
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Publication Date:
29 April 2002 (online)

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N 1-Acyl-, N 1-aryl-N 2-arylformamidines 4 and N 1,N 2-dialkyl C-acylamidines 6 result from the acylation of the N 1-silylformamidines 2a and C-silyl amidines 2b,c respectively. The latter are obtained by the hydrosilylation of aryl- and alkylcarbodiimides with the pentacoordinated silicon hydride 1.

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