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Synlett 1993; 1993(2): 163-164
DOI: 10.1055/s-1993-22389
DOI: 10.1055/s-1993-22389
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A Construction of Polyoxygenated cis and trans Decalin Systems by an Intramolecular Aldol Reaction
Further Information
Publication History
Publication Date:
19 March 2002 (online)
A straightforward construction of polyoxygenated decalins is described. The synthesis is based on the acid catalysed addition of a furan to an activated enone, followed by oxidation of the furan ring. The intermediate 1-4 dicarbonyl compound gives access to decalins through a spontaneous aldolisation. Control of the stereochemistry is discussed.