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Synlett 1994; 1994(9): 723-724
DOI: 10.1055/s-1994-22985
DOI: 10.1055/s-1994-22985
letter
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Bismuth (III) Chloride - Catalyzed Chlorination of Alcohols by Chlorosilanes1
Further Information
Publication History
Publication Date:
18 September 2002 (online)
In the presence of catalytic amounts of BiCl3, chloromethylsilanes could be used as chlorinating agents of alcohols and alkoxysilanes. At rt , t-butanolysis of polychlorosilanes led to polysiloxanes in quantitative yield.