Download PDF
Synlett 1994; 1994(11): 952-954
DOI: 10.1055/s-1994-23061
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Straightforward Synthesis and Reactivity of Polymer-supported Organotin Hydrides

Gilles Dumartin* , Géraldine Ruel, Jamil Kharboutli, Bernard Delmond, Marie-Françoise Connil, Bernard Jousseaume, Michel Pereyre
  • *Laboratoire de Chimie Organique et Organométallique, URA 35 CNRS, Université Bordeaux 1, 351, cours de la Libération, 33405-Talence Cedex, France
Further Information

Publication History

Publication Date:
22 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Polymer-supported organotin hydrides were prepared by the reaction of ω-haloalkylpolystyrenes with hydridodibutylstannyllithium. The stannyl group was separated from the phenyl ring by a two-, three- or four carbon spacer. These polymers were found to contain 0.8 to 1.4 mmole SnH per gram. The reducing ability of the polymer-supported organotin hydrides was monitored by reaction with haloalkanes. The amount of organotin residues was estimated.

      >