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Synlett 1996; 1996(10): 1004-1006
DOI: 10.1055/s-1996-5636
DOI: 10.1055/s-1996-5636
letter
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Direct Oxidation of Organoboranes with Oxygen in Perfluoroalkanes
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Diethylorganoboranes obtained by the hydroboration of alkenes with Et2BH are cleanly oxidized with oxygen in bromoperfluorooctane in good yields. Remarkably, the oxidation of secondary alkylboranes proceeds under these conditions with retention of configuration.
Oxidation - Oxygen - Boranes - Perfluoroalkanes