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Synlett 1996; 1996(12): 1211-1212
DOI: 10.1055/s-1996-5728
DOI: 10.1055/s-1996-5728
letter
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A Convenient Method for the Synthesis of Bis(trialkylphosphine)-Boranes Bearing Two Phospholanes
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Borane complexes of several trialkyl-type C 2-symmetric diphosphines bearing two chiral phospholanes were prepared by the reaction employing a lithium salt of a (2S,5S)-2,5-dimethylphospholane-borane complex which was formed in situ from a borane complex of (2S,5S)-2,5-dimethyl-1-phenylphospholane.
trialkylphosphine - phosphine-borane - chiral phospholane - diphosphine ligand - lipase-catalyzed esterification