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Synlett 1998; 1998(12): 1411-1413
DOI: 10.1055/s-1998-1939
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Synthesis of 1-Alkene-1,3-Sultones from 2,3-Epoxy-Alkanesulfonyl Chlorides

Bianca F. Bonini* , Gerjan Kemperman, Sander T. H. Willems, Mariafrancesca Fochi, Germana Mazzanti, Binne Zwanenburg
  • *Dipartimento di Chimica Organica "A. Mangini", Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy; Fax + 39 (0) 51 6 44 36 54; E-mail: bonini@ms.fci.unibo.it
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Publication History

Publication Date:
31 December 2000 (online)

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Dehydrochlorination of α,β-epoxy sulfonyl chlorides 3 leads to 1-alkene-1,3-sultones 1 most probably via epoxy sulfenes 2.

1-alkene-1,3-sultone - 2,3-epoxy-alkanesulfonyl chloride - epoxy sulfene - methyl trifluoromethyl dioxirane

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