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Synlett 2001; 2001(5): 0715-0717
DOI: 10.1055/s-2001-13369
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Highly Efficient Phosphazene Base-Catalyzed Michael Addition of β-Ketoesters in Water

David Bensa* , Jean-Michel Brunel, Gérard Buono, Jean Rodriguez
  • *Laboratoire RéSo, Réactivité en Synthèses Organique, boîte D12, UMR CNRS 6516, Faculté de St Jérôme, 13397 Marseille cedex 20, France; E-mail: Jean.Rodriguez@reso.u-3mrs.fr
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Publication Date:
31 December 2001 (online)

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Michael addition of various β-ketoesters with several Michael acceptors in water containing 10 mol% of N-phenyltris(dimethylamino)iminophosphorane results in high yield conversion to the corresponding adducts.

β-ketoesters - Michael addition - phosphazene base - water

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