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DOI: 10.1055/a-1765-7383
Recent Advances in Radical Reactions of Vinyl Triflates and Their Derivatives
This work was partially supported by the Asahi Glass Foundation, Yamaguchi University, the Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Young Scientists (B) (16K17869 and 18K14222), the Hattori Hokokai Foundation, the Yamagin Regional Enterprise Support Foundation, the Tobe Maki Scholarship Foundation, Daicel Corporation, the JGC-S Scholarship Foundation, and the Kyoto Technoscience Center.
Abstract
Vinyl triflates are valuable precursors for vinyl cations and vinyl carbenes and serve as electrophiles in transition-metal-catalyzed cross-coupling reactions. However, the scope of radical reactions involving vinyl triflates has been very limited until recently. In this short review, we summarize the recent development on two categories of radical reactions involving vinyl triflates, i.e., radical trifluoromethylations and radical non-trifluoromethylations of vinyl triflates.
1 I ntroduction to Vinyl Triflates
2 Earlier Work on Radical Reactions of Vinyl Triflates
3 Radical Trifluoromethylations of Vinyl Triflates and Their Derivatives
4 Radical Non-Trifluoromethylation of Vinyl Triflates
5 Conclusions and Outlook
Publikationsverlauf
Eingereicht: 06. Januar 2022
Angenommen nach Revision: 08. Februar 2022
Accepted Manuscript online:
08. Februar 2022
Artikel online veröffentlicht:
29. März 2022
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