Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds

Tieqiao Chen; Qihang Tan; Xue Liu; Long Liu; Tianzeng Huang; Li-Biao Han

doi:10.1055/s-0040-1707286

Synthesis, Inhaltsverzeichnis

Synthesis 2021; 53(01): 95-106
DOI: 10.1055/s-0040-1707286

short review

Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds

Authors

Tieqiao Chen∗

^aKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan University, Haikou, 570228, P. R. of China eMail: chentieqiao@hnu.edu.cn
Qihang Tan

^aKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan University, Haikou, 570228, P. R. of China eMail: chentieqiao@hnu.edu.cn
Xue Liu

^aKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan University, Haikou, 570228, P. R. of China eMail: chentieqiao@hnu.edu.cn
Long Liu

^aKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan University, Haikou, 570228, P. R. of China eMail: chentieqiao@hnu.edu.cn
Tianzeng Huang

^aKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan University, Haikou, 570228, P. R. of China eMail: chentieqiao@hnu.edu.cn
Li-Biao Han∗

^bDivision of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan eMail: libiao-han@aist.go.jp

Abstract

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Abstract

Herein, we highlight advances in the phosphorylation of readily available carboxylic acids and their derivatives forming synthetically important P(O)–sp³C, P(O)–sp²C, and P(O)–spC bonds, with an emphasis on the results demonstrated since 2010. This review examines the challenges associated with the use of this strategy for the synthesis of organophosphorus compounds and details advances in the design of catalytic systems that suppress these problems thus resulting in notable progress. Mechanistic details are discussed where available.

1 Introduction

2 Formation of P(O)–sp³C Bonds

3 Formation of P(O)–sp²C Bonds

4 Formation of P(O)–spC Bonds

5 Outlook and Conclusion

Key words

phosphorylation - carboxylic acids - decarboxylation - decarbonylation - cross coupling

Volltext

Referenzen

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