DOI: 10.1055/s-00000131

Synfacts

Issue 09 · Volume 21 · September 2025 DOI: 10.1055/s-015-62114

Synthesis of Natural Products

  • z867

    All PDFs of this category

  • 867

    Total Synthesis of (±)-Lycojapomines A and B

  • 868

    Total Synthesis of (+)-Swinhoeisterol A

  • 869

    Total Synthesis of (±)-Penisuloxazin A

  • 870

    Total Synthesis of (+)-Rhodocorane L

  • 871

    Total Synthesis of (±)-Streptoglyceride A

  • 872

    Total Synthesis of (±)-Tubingensin A

  • 873

    Total Synthesis of (+)-Cyanthiwigin U

    • Synthesis of Heterocycles

  • z875

    All PDFs of this category

  • 875

    Synthesis and Properties of Bicyclic Fluorinated Piperidine Derivatives

  • 876

    Synthesis of 6-Azabicyclo[3.1.1]heptanes Through Light-Mediated Intramolecular [2+2] Cycloaddition

  • 877

    Diastereoselective Synthesis of Functionalized (Hetero)cyclohexane-4-carboxylate Derivatives

  • 878

    Facile Access to 7-Azaindolines and the Corresponding Azaindoles

  • 879

    Conversion of Iodo-Bicyclopentanes Into Aminomethyl Bicyclobutanes

  • 880

    Diastereoselective Synthesis of Tetrahydrofuran/Tetrahydropyran Derivatives

  • 881

    Synthesis of 3-Azetidinones through Light-Driven C–C Bond Formation

  • 882

    Facile Introduction of the SF5-Moiety Into Azetidines and Cyclobutanes Using a Shelf-Stable Reagent

  • 883

    Synthesis of Functionalized Bicyclic Heterocycles as Bioisosteres for meta-Substituted (Hetero)arenes

  • 884

    Facile Access to Spiroketals through Electrochemistry

  • 885

    Iron-Catalyzed Cross-Electrophile Coupling

  • 886

    C(sp2)–C(sp3) Bond Formation for Pyridines

  • 887

    meta-Selective Fluorination of Pyridine Derivatives

  • 888

    Diastereoselective α-(Hetero)Arylation of 4-Silyloxy Piperidines

  • 889

    α-Functionalization of Pyrrolidines to Access Spirocyclic Proline Derivatives

    • Synthesis of Materials and Unnatural Products

  • z891

    All PDFs of this category

  • 891

    Light-Triggered, High-Resolution Doping of Organic Semiconductors

  • 892

    Azulene-Embedded PAHs from [2+2+1] Annulation–Oxidation

  • 893

    Preparation and Reactivity of a Stable Hexaphenyl Diphosphonium Dication

  • 894

    1,4-Diboraanthracenes via 1,2-Naphthodiboretes

  • 895

    Boron–Carbon Diradical-Mediated Boracycles

  • 896

    Pyrazole-Enabled Controlled SNAr Polymerization of Arynes

  • 897

    Carbon Dioxide Mediated Controlled Anionic Polymerization

  • 898

    Cyclic Olefin Polymers from Group-Transfer Radical Cyclopolymerization

  • 899

    Bifunctional Catalysts for Ring-Opening Alternating Copolymerization

  • 900

    Single Catalyst for Olefin Block Copolymers

    • Metals in Synthesis

  • z901

    All PDFs of this category

  • 901

    Photochemical Copper-Catalyzed Chloroacylation of Unsaturated C–C Bonds

  • 902

    Copper-Mediated Deacetylative Fluorination of Methyl Ketones to Alkyl Fluorides

  • 903

    Synthesis of Diborylamines via the Iron-Catalyzed Hydroboration of Nitriles

  • 904

    Carbonylation of Gaseous Alkanes into Thioesters under Photoinduced Copper Catalysis

  • 905

    Dual-Metal-Catalyzed Shuttling of Isomeric Mixtures to Stereodefined Functionalized Products

  • 906

    Synthesis of Tertiary Nitro Compounds by Cobalt-Catalyzed Hydronitration of Alkenes

  • 907

    Synthesis of Protected Unnatural Amino Acids Enabled by an Ylide-Functionalized Phosphine

  • 908

    Palladium-Catalyzed Aminocarbonylation of Iodoarenes with Carbon Monoxide and Nitroarenes

  • 909

    Synthesis of Diastereomerically Enriched (Thio)phosphonates from Phosphinic Dichlorides

  • 910

    Synthesis of Triarylmethanes from Acylsilanes and Electron-Rich Arenes by Photoinduced Copper Catalysis

  • 911

    Easy Access to E- and Z-Alkenes through Cobalt-Catalyzed Semihydrogenation of Alkynes

  • 912

    Dealkylation of Aryl Alkyl Ethers under Photoinduced Copper Catalysis

  • 913

    Stereoselective Synthesis of 1,3-Diols from Vinyl-Substituted Cyclic Carbonates under Nickel Catalysis

  • 914

    Iridium-Photocatalyzed Difunctionalization of Alkenes Using N-Benzoyloxyamides

  • 915

    An Umpolung Approach towards the α-Allylation of α-Iminoesters under Cobalt Catalysis

  • 916

    A Novel Agent for the Metal-Catalyzed Methylthiolation of Aryl Electrophiles

  • 917

    Access to α-Amino Amides through Asymmetric Copper Amino Propargylation

  • 918

    Synthesis of 1,2-Dicarboxylic Acids from Unactivated Alkynes with CO2 under Iridium Photocatalysis

  • 919

    Enantioselective Synthesis of Indoyl Chromans Using a Gold–Catalyzed Arylative Cyclization

  • 920

    Palladium-Catalyzed β‑Selective C(sp3)–H Fluorination of Amides

  • 921

    Regulating Back-Electron Transfer in Nickel-Catalyzed Cross-Electrophile Couplings

  • 922

    Asymmetric Decarboxylative N-Alkylation of Amines Enabled by Dual Cobalt and Acridine Photocatalysis

  • 923

    Enantioselective Synthesis of Bis-Heterocycles via Palladium Domino Catalysis

  • 924

    Asymmetric Synthesis of [5,5]-Fused Bicycles by Nickel-Catalyzed 1,3-Cyclotelomerization of Butadiene

  • 925

    Highly Selective Azetidine Synthesis by Boryl Allylation of Azetines

  • 926

    Rhodium-Catalyzed C–C Bond Activation

    • Polymer-Supported Synthesis

  • z927

    All PDFs of this category

  • 927

    Electrocatalytic Hydrogenation of Olefins

  • 928

    Palladium-Catalyzed Regio- and Enantioselective C–H Alkenylation under Electrocatalytic Redox Conditions

  • 929

    A Carbon-Supported Ag5Cu4 Nanocluster Catalyst for the Knoevenagel Condensation

  • 930

    Enantioselective Minisci-Type Addition to Heteroarenes Using Mesoporous g-C3N4 under Red-Light Irradiation

  • 931

    Deuteration of Hydrosilanes Using Ruthenium Nanoparticles on γ-Al2O3

  • 932

    A Nickel-Incorporated Pyridyl-Quinoline-Based COF for Cross-Couplings of Aryl Halides and Nucleophiles

  • 933

    A Metal-Free Ionic Porous Polymer Gel Catalyzed N-Formylation of Amines and Amides under CO2

  • 934

    A Polymer-Supported Palladium Catalyst for Tandem Borylation/Suzuki Coupling of Aryl Iodides

  • 935

    Formation of Phenylbenzimidoyl Cyanide Derivatives by Electrochemical Cyanation of Imines in Acetonitrile

  • 936

    A Polymeric Homochiral Manganese Catalyst for Asymmetric Benzylic Oxidation and Olefin Epoxidation

    • Organo- and Biocatalysis

  • z937

    All PDFs of this category

  • 937

    Chiral Calcium Phosphate-Catalyzed Transfer Hydrogenation of β-Trifluoromethylated Nitroalkenes

  • 938

    Redox and Nucleophilic Catalysis of N-Heterocyclic Phosphinidene

  • 939

    Conquering Back Electron Transfer in Photochemistry

  • 940

    Chiral Ammonium Salt Catalyzed Synthesis of α-Tertiary Amines from Alkynyl Ketimines

  • 941

    Verdazyl Radicals as Organocatalysts for Redox-Neutral C–C Bond Formation

  • 942

    Stereoablative Enantioconvergent Hydrolysis of γ-Chiral Oximes

  • 943

    Harnessing Visible Light for Stereoselective Hydro- and Iodotrifluoromethylation of Alkynes

  • 944

    Dispersion-Driven Design of a General Asymmetric Transfer Hydrogenation Catalyst

  • 945

    Organophotocatalytic Transformation of Unactivated Olefins into α-CF3 Amines Catalyzed by Thiols

    • Innovative Drug Discovery and Development

  • z947

    All PDFs of this category

  • 947

    Near-Infrared-Activated Pd@Au Nanorods for Prodrug and Prodye Uncaging

  • 948

    Reductive Sulfonamidation of Amides via Zirconium Hydride Catalysis

  • 949

    HAT/XAT-Enabled Selective Radical Monohalogenation

  • 950

    One-Pot Migrative Reductive Amination of Ketones

  • 951

    Ex-Chiral-Pool Synthesis of RIPK1 Inhibitor GDC-8264

  • 952

    Tunable, Platinum(IV)-Based Photocages via Click Ligation

  • 953

    Synthesis of Morphine Analogues with a Carbocyclic E-Ring

  • 954

    No Mixing Required: “Cocktail” Probe Unites Fluorophores for Unimolecular Multi-ROS Imaging

  • 955

    Improved Stereoselective Synthesis of Delgocitinib

  • 956

    Allylic Extension of Terminal Olefins

  • 957

    Radiolabeled Arylazopyrazole Ligand Reveals Light-Controlled Binding Kinetics at a GPCR

    • Peptide Chemistry

  • z959

    All PDFs of this category

  • 959

    Introduction of Carbazolyl Phthalonitrile into Peptide Chains

  • 960

    Nickel(II)-Catalyzed Stereodivergent Reactions of N-Azidoacetyl Thioimides with Aromatic Acetals

  • 961

    Glycine Derivative Functionalization with Alkyl-trifluoromethyl Groups

  • 962

    Light-Driven Decarboxylative Oxygenation of Amino Acids and Peptides Using Diphenyl Diselenide

  • 963

    Synthesis of Pyrazinylglycine Derivatives through Dechlorinative Pyrazinylation

  • 964

    Trimethylsilyl Bromide Promoted Ligation of Tryptophan and Cysteine

  • 965

    Desulfurative Functionalization of Cysteine

  • 966

    N-Arylation of Peptides and Their Ligation in Organic Solvent

  • 967

    Synthesis of Thioarylated Cysteine and Cysteine-Containing Peptides

  • 968

    Copper-Catalyzed Late-Stage Functionalization for the Synthesis of Phenothiazine-Based Cyclopeptides

  • 969

    Zinc Chloride Mediated Claisen Rearrangement for the Synthesis of Allenic Amino Acids

    • Flow Chemistry

  • z971

    All PDFs of this category

  • 971

    Electrochemical Generation of CO and Palladium-Catalyzed Carbonylation of Aryl Iodides in Flow

  • 972

    N-Benzylation of Amides under Batch and Continuous Flow Conditions Using a Zeolite-Supported Ru Catalyst

  • 973

    Photochemical Synthesis of Pyridino[2,1-b]quinazolinones Enhanced by Flow

    • Correction

  • 975

    Correction: Total Synthesis of (±)-Melohemsine K