Synthesis 2022; 54(12): 2749-2764
DOI: 10.1055/a-1755-3832
short review

Synthetic Approaches for the Construction of Five- and Six-Membered Silaazacycles

Wanshu Wang
,
Lu Gao
,
Zhenlei Song
We are grateful to financial support from the National Natural Science Foundation of China (21921002, 22171191), the Open Research Fund of Chengdu University of Traditional Chinese Medicine Key Laboratory of Systematic Research of Distinctive Chinese Medicine Resources in Southwest China (2020LF2003), and the Science and Technology Department of Sichuan Province (2020YFS0186).


Abstract

Silaazacycles (or azasilacycles), containing both nitrogen and silicon atoms, are appealing ring structures in the development of silicon-containing functional molecules. The development of general and efficient methods towards these motifs has therefore attracted considerable attention from synthetic chemists. This short review intends to highlight representative advances in the synthesis of five- and six-membered silaazacycles.

1 Introduction

2 Five-Membered Silaazacycles

2.1 Five-Membered Silaazacycles bearing a 1,2-N/Si Moiety

2.2 Five-Membered Silaazacycles bearing a 1,3-N/Si Moiety

3 Six-Membered Silaazacycles

3.1 Six-Membered Silaazacycles bearing a 1,2-N/Si Moiety

3.2 Six-Membered Silaazacycles bearing a 1,3-N/Si Moiety

3.3 Six-Membered Silaazacycles bearing a 1,4-N/Si Moiety

4 Conclusion



Publikationsverlauf

Eingereicht: 26. Dezember 2021

Angenommen nach Revision: 31. Januar 2022

Accepted Manuscript online:
31. Januar 2022

Artikel online veröffentlicht:
09. März 2022

© 2022. Thieme. All rights reserved

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Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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