Synthesis

Issue 05 · March 2019

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table of contents
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50 Years SYNTHESIS – Golden Anniversary Issue Part II
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A31
Zanda, Matteo:
SYNFORM ISSUE 2019/3
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review
985
Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir:
Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
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short review
1006
Zard, Samir Z.:
Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group
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1021
Crawford, Jennifer M.; Sigman, Matthew S.:
Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
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1037
Ferrer, Sofia; Echavarren, Antonio M.:
Synthesis of Bullvalenes: Classical Approaches and Recent Developments
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1049
Maraswami, Manikantha; Loh, Teck-Peng:
Transition-Metal-Catalyzed Alkenyl sp² C–H Activation: A Short Account
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1063
Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.:
Advancements in Visible-Light-Enabled Radical C(sp)²–H Alkylation of (Hetero)arenes
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1073
Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline:
Pyrroles as Dienes in (4+3) Cycloadditions
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1087
Gagosz, Fabien:
Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry
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1100
Groso, Emilia J.; Schindler, Corinna S.:
Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles
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feature
1115
Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias:
Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method
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1123
Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine:
Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst
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1135
Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.:
A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene
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1139
Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke:
General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S_NAr Cyclizations of Aryl Fluorides
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1157
Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert:
Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
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1171
Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong:
Bromine-Radical-Mediated Site-Selective Allylation of C(sp³)–H Bonds
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1178
Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald:
An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
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1185
Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki:
Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
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1196
Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert:
GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for ¹⁸F-Positron Emission Tomography (PET)
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1207
McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva:
Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH₂SiMe₃)₃ Metalation Reactions
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1216
Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni:
Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids
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paper
1225
Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian:
Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups
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1235
Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.:
Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block
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1243
Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus:
Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions
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1253
Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.:
Lewis Acid Promoted Trapping of Chiral Aza-enolates
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1263
Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor:
Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation
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1273
Baldauf, Simon; Bode, Jeffrey W.:
Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations
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1284
Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz:
Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature
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