Synfacts
Issue 04 · April 2009
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A21
SYNFORM
ISSUE 2009/03
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Synthesis of Natural Products and Potential Drugs
z351
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0351
Synthesis of Aburatubolactam A
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0352
Synthesis of Sesquisabinene and Epoxysesquithujene
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0353
Synthesis of (+)-Cortistatin A
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0354
Formal Synthesis of (-)-Kendomycin
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0355
Synthesis of Callystatin A
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PDF (69 kb)
0356
Formal Synthesis of Tamiflu
®
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0357
Synthesis of (-)-Podophyllotoxin
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0358
Total Synthesis of (-)Clavirolide C
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0359
Synthesis of (+)-Lepadin B
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0360
Synthesis of (-)-Allosecurinine
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0361
Synthesis of Myriocin
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0362
Synthesis of Haterumalide NC
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0363
Synthesis of (-)-Cephalotaxine
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0364
Synthesis of Ventricosene
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0365
Synthesis of ()-Dibromoagelaspongin
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Synthesis of Heterocycles
z367
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0367
Lanthanide Triflate Catalyzed Hetero-annulation Route to Tetrahydroquinolines
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0368
Lithiated Dithiane Ring Opening of N-Protected Aziridines
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0369
Microwave-Assisted Diels-Alder Approach to 4-Substituted Indoles
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0370
Polysubstituted Pyrroles from (
Z
)-Enynols
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0371
Nucleophilic Fluorination of 3-Cyanopyridines
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0372
Synthesis of Functionalized Pyridazines from 1,2-Diaza-1,3-butadienes
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0373
Synthesis of
N
-Hydroxypyrroles Using N-Selective Nucleophilicity of Oximes
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0374
Synthesis of Disubstituted Pyrroles from
1,3-Dicarbonyls and Azides
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0375
Synthesis of Substituted Pyrroles from Skipped Diynes
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0376
Multicomponent Synthesis of Benzothiazepinones
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0377
Synthesis of Imidazoles and Oxazoles by Aldimine Cross-Coupling
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0378
Synthesis of Benzothiazines via an Intramolecular Thioamide
S
-Michael Addition
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0379
Synthesis of Multisubstituted Pyridines from α-Diazocarbonyl Derivatives
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0380
Synthesis of Pyrimidoquinolines via the Pictet-Spengler Reaction
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Synthesis of Materials and Unnatural Products
z381
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0381
Synthetic β-Sheet Mimic
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0382
Luminol-Type Polymers
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0383
Radical Approach to Cross-Linking
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0384
Cyanide Detection with Heterocyclic Quinoid Compounds
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0385
Synthesis of Near-Infrared Emitting Naphthalimide Dyes
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0386
Macrocyclic Polyfluorenes through Sacrificial Porphyrin Templates
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0387
exo
-Functionalization of Calixarene via a
p
-Bromodienone
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0388
Bright Near-Infrared Dyes
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0389
Attaching Four-Membered Rings to Dibenzobarrelene
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0390
Organoboron 1,3-Diketonate Polymers through Post-Polymerization Chelation
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0391
Calixarene-Templated Synthesis of Heteracalixarenes
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0392
Photochemical Generation of Enediyne for Bergman Cyclization
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0393
Polyisocyanurates as Catalyst Support Systems
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z395
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0395
Palladium-Catalyzed Addition of Arylboronic Acids to
N
-Benzylisatin
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0396
Ru-Hydrogenation of Bulky Ketones with a Tridentate Ligand
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0397
Synthesis of P-Stereogenic Centers Through Ring-Closing Metathesis
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0398
Iron-Catalyzed 1,4-Addition of α-Olefins to 1,3-Dienes
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0399
Palldium-Catalyzed Synthesis of Epoxides by Carboetherification
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0400
1,3-Dipolar Cycloaddition of Azomethine Ylides with α,β-Unsaturated Ketones
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0401
Palladium-Catalyzed Asymmetric Reductive Amination of Ketones
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0402
Synthesis of 5-Alkoxycyclohex-2-enones by Ring-Closing Metathesis
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0403
Planar-Chiral Catalyst for Friedel-Crafts Alkylation of Indoles
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0404
Zirconium-Catalyzed Friedel-Crafts Alkylation of Pyrrole
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0405
Titanium-Catalyzed Ring Opening of
meso
-Aziridine
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0406
Highly Reactive Chiral Pincer Ruthenium Complexes for Reduction of Ketones
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0407
Lewis Acid Catalyzed C-H Bond Functionalization/Hydride Transfer
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0408
Tin-Free Radical Conjugate Addition of Silanes
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0409
Siloxycarbene Facilitated C-H Functionalization
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0410
Reagent Control in Asymmetric Allylboration of Chiral Aldehydes
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0411
Inverse Electron Demand HDA of 2-Alkenoyl
N
-Oxides
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0412
Asymmetric Hydrogenation of Cyclic Enamines
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0413
Asymmetric Gold-Catalyzed Enyne Cyclization
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0414
BINOL Derivative Catalyzed Enantioselective Diethylzinc Alkylation
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0415
Iron-Catalyzed Asymmetric Transfer Hydrogenation of Ketones
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0416
Recoverable Ligand for Sharpless Asymmetric Epoxidations
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0417
Palladium-Catalyzed Direct Cross-Coupling of Alkenes and Acrylates
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0418
Diastereoselective Ti(IV) Enolate Glycosylation
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0419
Rhodium/Me-CATPHOS-Catalyzed Hydrogenation
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0420
Copper-Catalyzed Three-Component Reactions to Benzoxazines
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0421
Regiodivergent Resolution of Unsymmetrical Oxabicyclic Alkenes
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0422
Palladium-Catalyzed Cross-Coupling of Benzyl Bromides with α-Aryldiazoesters
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0423
Desymmetrizing Hydroformylation/Carbonyl Ene Cyclization
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0424
Yttrium-Catalyzed Desymmetrization of Aziridines
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Metal-Mediated Synthesis
z425
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0425
Efficient Cobalt-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Bromides
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0426
Oxa- and Azacycles via a Novel Iron-Catalyzed Prins Cyclization
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0427
Copper-Facilitated Suzuki Cross-Coupling of 2-Heterocyclic Boronates
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0428
ZnBr
2
-Catalyzed Oxidation of Alcohols by Diethyl Azodicarboxylate
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0429
Base-Mediated Halogenation of Acidic Aryl C-H Bonds at Higher Temperatures
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0430
Intramolecular Hydroalkoxylation of Alkynyl Alcohols by Lanthanide Catalysts
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0431
Hydroformylation of Homoallylic Azides: A Rapid Approach toward Alkaloids
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0432
Unsymmetrical Nickel-Catalyzed Oxidative Coupling of Terminal Alkynes
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0433
Direct Amination of Aromatic Boronic Acids with Aqueous Ammonia
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0434
Copper-Catalyzed Tandem Synthesis of N-Fused Isoquinolines
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0435
Scandium-Catalyzed Homologation of Cycloalkanones with Diazo Compounds
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0436
Pd-Catalyzed C-H Activation/Aryl-Aryl Coupling of Aromatic Acids
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0437
RuCl
3
-Catalyzed Allylation of Aldehydes with Allyl Acetate
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0438
Stereo- and Regioselective Synthesis of Amino Alcohols via Lithiation/Borylation of Aziridines
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0439
Highly Efficient Au(I)-Catalyzed Alkyne Hydration
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Organo- and Biocatalysis
z441
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0441
α-Alkylation of Aldehydes by S
N
1-Type Reaction of Alcohols
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0442
Asymmetric Hydrogenation of Enamides
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0443
Brønsted Acid-Thiourea Co-Catalysis
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0444
A Versatile Synthesis of Lactones via a NHC-Catalyzed Ring Expansion
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0445
Organocatalytic Oxidative Cleavage of C-C Double and Triple Bonds
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0446
Amino Sulfonamide Catalyst for the Direct Mannich Reaction of
N
-Boc Imines
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0447
A Trifunctional Catalyst for a Rapid Aza-Morita-Baylis-Hillman Reaction
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0448
A Stereoselective Domino Reaction Leading to a Pyrrolizidine Skeleton
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0449
Intramolecular Friedel-Crafts-Type α-Arylation of Aldehydes
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0450
Iminium Catalysis with α-Alkyl Acroleins
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Polymer-Supported Synthesis
z451
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0451
Michael Additions Catalyzed by Bifunctional Mesoporous Silica
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0452
Copper Zeolites Catalyzed Homocoupling of Terminal Alkynes
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0453
Transfer Dehydrogenation with Alumina-Supported Ir Pincer Complexes
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0454
Heck Reaction with SBA-15-Supported Palladium Catalyst
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0455
Solid-Phase Synthesis of Dimerizable Cationic Detergents for Gene Delivery
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0456
Silica Gel Immobilized Flavins for Photooxidation of Benzyl Alcohols
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0457
Synthesis of 1,2,3-Triazole Derivatives with Copper Nanoparticles in Water
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0458
Dimerization of 1,6-Diynes with Ionic Liquid Supported Nickel Complexes
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0459
Pd/HP20-Catalyzed Hydrogenation and Suzuki-Miyaura Coupling
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0460
RCM Reactions with a Ruthenium Micellar Catalyst
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0461
Dendritic Effect of Supported Proline-Based Catalysts for Aldol Reaction
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0462
cis
-Product Formation by Imprinted Palladium Silicate Promoted Heck Reaction
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0463
Monoalkylation of Primary Amines and
N
-Sulfinylamides Using Raney-Nickel
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0464
Olefination of Aldehydes Using PEG-Supported Iron(II) Porphyrin
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