DOI: 10.1055/s-00000131

Synfacts

Issue 01 · Volume 2010 · January 2010 DOI: 10.1055/s-002-20656

Synform

A1
SYNFORM ISSUE 2010/01

Synthesis of Natural Products and Potential Drugs

z1
All PDFs of this category
0001
Synthesis of (+)-Haplophytine
0002
Synthesis of Aspercyclide B
0003
Synthesis of (+)-Haplophytine
0004
Synthesis of Antibiotic TAN-1085
0005
Synthesis of Cyathin A3 and Cyathin B2
0006
Synthesis of (-)-Tetrahydrolipstatin
0007
Synthesis of Gloeosporone
0008
Synthesis of Berkelic Acid
0009
Synthesis of Haterumalide NA
0010
Synthesis of Ravuconazole
0011
CXCR4 Antagonist (GSK812397)
0012
Synthesis of (R)-Sitagliptin
0013
Synthesis of (-)-Bestatin
0014
Synthesis of (±)-Pallavicinolide
0015
Synthesis of (-)-Gymnodimine
0016
Synthesis of Resolvin E2
0017
Synthesis of Kendomycin
0018
Synthesis of Vannusal B
0019
Synthesis of (+)-Polyanthellin A
0020
Formal Synthesis of (±)-Platencin

Synthesis of Heterocycles

z21
All PDFs of this category
0021
Copper-Catalyzed Synthesis of 1,2,4-Triazoles
0022
FeCl3-Mediated Synthesis of Benzo[b]furans from α-Aryl Ketones
0023
Palladium-Catalyzed Synthesis of Pyrroloisoquinolines and Isoindoles
0024
Cs2CO3-Promoted Synthesis of Substituted Oxazoles
0025
Rhodium-Catalyzed Synthesis of Pyrroles by [4+1] Cycloaddition
0026
Iron-Catalyzed Synthesis of 2-Aminobenzo-thiazoles
0027
Cerium(III)-Catalyzed Synthesis of N-Arylpyrrolidines
0028
Rhodium-Catalyzed Enantioselective Synthesis of Phthalides
0029
Hydroamination Route to Pyridines and Pyrazines
0030
Gold-Catalyzed Synthesis of Quinolines
0031
CuBr-Catalyzed Synthesis of 2-Aminobenzo-thiazoles
0032
Acid-Mediated Synthesis of Benzofurans from Arylhydroxylamines
0033
One-Step Synthesis of Polysubstituted Pyrimidines
0034
Iodine-Catalyzed One-Pot Synthesis of 6H-Indoloquinoline Derivatives
0035
Gold-Catalyzed Synthesis of Pyrroles and Furans

Synthesis of Materials and Unnatural Products

z37
All PDFs of this category
0037
One Pot per Generation
0038
High Degree of Functionality from Click Chemistry Polymers
0039
Very High Short-Circuit Currents in Squaraine Solar Cells
0040
Programmable Tetraarylthiophenes
0041
Fullerene Allylation
0042
And ”Then There Was White"
0043
Packing-In Negative Charge with Azulenes
0044
High Fluorescent Quantum Yield Bis-N-Annulated Quatterylenebis(dicarboximide)
0045
Mechanofluorochromism in Organic Donor-Acceptor Dyes
0046
Reversing the Trend in Oxidative Addition
0047
Quinone-ly You
0048
An Easy Way to Trifluoromethanesulfanyls
0049
Ring Around the Porphyrins
0050
Synthesis of a Quinoidal Bisanthene
0051
Small Hydrocarbon Cages

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z53
All PDFs of this category
0053
cis-Selective Hydroboration of Allenes
0054
Asymmetric Diaza-Cope Rearrangement Employing α-Keto Esters
0055
Enantioselective Cyclopropanation of Allenes Catalyzed by a Rhodium(II) Complex
0056
Enantioselective Ring Opening of Propargyl Epoxides
0057
Zr- and Hf-Catalyzed Asymmetric Friedel-Crafts Alkylation of Indoles with Endiones
0058
Synthesis of Chiral Cyclobutenes with All-Carbon Quaternary Stereocenters
0059
Ir-Catalyzed Asymmetric Hydrogenation of 2-Aryl- and 2-Alkylquinolinium Salts
0060
Chiral 2,5-Dihydrofurans Via Tandem Lipase/Gold Catalysis
0061
Zirconium-Catalyzed Enantioselective Ring Opening of meso-Aziridines
0062
Palladium-Catalyzed Stereoselective Construction of Chromans
0063
Stereoselective Synthesis of 2-Methyl-3-butene-1,2-diols
0064
Diastereoselective Synthesis of Axially Chiral Biaryls
0065
Asymmetric Stereoablative Alkylation of 3-Halooxindoles
0066
Enantioselective Reduction of Quinoxalines
0067
Tandem Asymmetric Aza-Darzens/Ring-Opening Reactions
0068
Reduction of Lactones with Samarium Iodide
0069
Rhodium-Catalyzed Addition of Arylboroxines to N-Phosphinoyl Aldimines
0070
Rhodium-Catalyzed Conjugate Alkynylation with TMS-acetylene
0071
Palladium-Catalyzed Tandem Annulation of 2-Formylarylboronic Acids with Allenoates
0072
Addressing Selectivity in the Formation and Reactions of Spirodiepoxides
0073
Asymmetric Synthesis of Chiral 3,4-Dihydro-quinolin-2-ones
0074
Aluminum-Catalyzed Asymmetric Strecker Reaction
0075
Three-Component Diastereoselective Synthesis of Pyrrolidinones
0076
Catalytic Oxidative Desymmetrization of meso-Secondary Diols
0077
Copper-Catalyzed Asymmetric Allylic Arylation with Grignard Reagents
0078
Rhodium-Catalyzed Asymmetric Conjugate Alkynylation
0079
[2+2] Cycloadditions by Visible Light Photocatalysis
0080
Rhodium-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds
0081
Cationic Rh(I)/Ag(I) Complexes Catalyzed the Synthesis of Tetrasubstituted Alkenes
0082
Dicationic Pd(II)-Catalyzed Alkenylation of Glyoxylate with Vinylsilanes

Metal-Mediated Synthesis

z83
All PDFs of this category
0083
Titanium-Mediated Reductive Cross-Coupling of Aliphatic Imines
0084
Ni-Catalyzed Neopentylglycolborylation of Aryl Chlorides
0085
Palladium-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides
0086
Fe-Catalyzed C-H Functionalization and Coupling of Alcohols with Alkenes
0087
Palladium-Catalyzed Newman-Kwart Rearrangement of Thiocarbamates
0088
Heteroarylsulfonates in Iron-Catalyzed Coupling with Alkyl Grignard Reagents
0089
Iron-Catalyzed sp²-sp³ Cross-Coupling of Alkenylzinc Compounds
0090
Nucleophilic Addition of Alenylsilanes at the β-Position
0091
C=C Double Bond Formation via Coupling of N-Tosylhydrazones with Benzyl Halides
0092
Ru-Catalyzed Isomerization of Alkynediols and in situ Cyclization
0093
A Facile Gold-Catalyzed Synthesis of Heterocycles from Propargyl Alcohols
0094
Olefin Cyclopropanation by Sequential Radical Addition/Dechlorination
0095
CuX2-Mediated [4+2] Benzannulation for the Synthesis of Haloaromatic Compounds
0096
A Simple Cu-Catalyzed Synthesis of Phenols from Aryl Halides
0097
ZnCl2-Catalyzed Enantiospecific C(sp³)-C(sp³) Cross-Coupling Giving (Oligo)deoxypropionates

Organo- and Biocatalysis

z99
All PDFs of this category
0099
Combining Organo- and Biocatalysis
0100
A New Approach to Asymmetric DMAP Catalysis
0101
Cross-Aldol Reactions of Enolizable Aldehydes
0102
A Highly Efficient Chiral Amine-Thiourea Catalyst
0103
Desymmetrization of meso-Aziridines with Thiols
0104
Styrylisoxazoles as Cinnamate Equivalents
0105
Combining Gold- and Organocatalysis
0106
Enantioselective Base-Free Phase-Transfer Reaction
0107
Catalysts in a Bottle
0108
Gram-Scale Strecker Synthesis of Unnatural α-Amino Acids
0109
Enantioselective Steglich Rearrangement Using Isothiourea Catalysts
0110
Cascade Reactions of Amphoteric Amino Aldehydes
0111
Mechanistic Insight in an Improved Allylboration of Ketones
0112
Enantioselective Sulfonylation of Polyols

Polymer-Supported Synthesis

z113
All PDFs of this category
0113
Mukaiyama Aldol Reaction with Sc(III)-USY
0114
Huisgen Reaction of Organic Azides and Alkynes with Cu(OH)x/TiO2
0115
Parallel Solid-Phase Synthesis of Iodinated Analogues of Rimonabant
0116
Base-Controlled Sequential C-S Bond Formation by CuSO4/Al2O3 Catalyst
0117
Silica-Alumina-Supported Catalysts for Efficient 1,4-Addition Reactions
0118
Amide Synthesis from Alcohols and Amines with Ag/Al2O3
0119
Three-Component Synthesis of Substituted Pyridines with Silica Nanoparticles
0120
Asymmetric Aldol Reaction with Polystyrene-Supported Proline-Based Catalysts
0121
Aerobic Oxidation of Alcohols with Gold Nanoparticles Supported on Cs2CO3
0122
Carbon-Carbon Multiple Bond Reduction by MOF with Hydrazine
0123
Suzuki Coupling in Water with Pd-NHC Immobilized on Fe3O4/Ionic Liquid
0124
C-N/C-O Bond Formation with CuI Nanoparticles
0125
Suzuki-Miyaura Coupling with Sn6O6-Pd Nanocomposites
0126
Aerobic Oxidation of Alcohols with Ruthenium on Carbon

Addenda and Errata

0127
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides
0127
Synthesis of Kapakahines B and F
0127
Biaryl Cross Coupling Catalyzed by Fe/Co/Ni-Fluorides and NHC Ligands